Integrating Maxwell-Boltzmann speed distribution

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SUMMARY

The discussion focuses on integrating the Maxwell-Boltzmann speed distribution, specifically finding the root mean square speed (vrms) by evaluating the definite integral of P(v)*v^2 from 0 to infinity. The integral simplifies to (v^4)*exp(-mv^2/kT) after moving constants outside. A substitution is necessary, setting x = v*sqrt(m/(2kT)), which resolves the integration challenge. The final expression for vrms is confirmed to be 3kT/m, with adjustments made for the differential operator.

PREREQUISITES
  • Understanding of Maxwell-Boltzmann statistics
  • Familiarity with definite integrals and integration techniques
  • Knowledge of thermodynamic variables such as mass (m), Boltzmann constant (k), and temperature (T)
  • Experience with substitution methods in calculus
NEXT STEPS
  • Study the derivation of the Maxwell-Boltzmann speed distribution
  • Learn about the application of definite integrals in statistical mechanics
  • Explore the concept of root mean square speed in kinetic theory
  • Investigate the relationship between temperature and molecular speed distributions
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Students and researchers in physics, particularly those studying statistical mechanics and thermodynamics, as well as anyone interested in the mathematical foundations of molecular speed distributions.

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Homework Statement



Let P(v) represent the Maxwell-Boltzmann speed distribution. Basically what it comes down to is that I have to find the definite integral (0,inf) of P(v)*v^2 and get vrms from this.

Homework Equations



We are given the definite integral from 0 to inf for the function (x^4)*exp(-x^2), which is (3/8)*Sqrt(Pi).

The Attempt at a Solution



I first move all the constants in front of the integral and then the integral simplifies to (v^4)*exp(-mv^2/kT). However, I have no idea what to do with the constants stuck in the exponent. How would I continue from here?

Thank you beforehand.
 
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You have to make a substitution. Set:
x=v*sqrt(m/(kT)). (Except I think it's really x=v*sqrt(m/(2kT)) and you forgot the 2. E= 1/2 mv^2).
 
Thanks, that seems to be a working solution! Do you know what the answer should be? 3kT/m? For some reason I get Sqrt(9kT/2m).

EDIT: Forgot to replace dv with the corresponding operator for x, dx*[(m/2kT)^(-1/2)]. Got it now!
 
Last edited:

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