Ionizing a covalently-bonded molecule?

  • Context: Chemistry 
  • Thread starter Thread starter bigplanet401
  • Start date Start date
  • Tags Tags
    Molecule
Click For Summary
SUMMARY

When a water molecule (H2O) is impacted by high-energy electrons or photons, it can undergo ionization, resulting in the formation of ions such as H+ and OH-. The reaction can be represented as e- + H2O → H+ + OH + 2e-. Additionally, photons can induce reactions like γ + H2O → H2 + O, demonstrating the molecule's ability to absorb energy. Ionizing radiation, including cosmic rays, can lead to the formation of radicals, emphasizing the significant impact of high-energy interactions on covalently-bonded molecules.

PREREQUISITES
  • Understanding of ionizing radiation and its effects
  • Basic knowledge of chemical reactions involving water
  • Familiarity with molecular ionization processes
  • Concept of radical formation in chemistry
NEXT STEPS
  • Research the mechanisms of ionization in water molecules under radiation exposure
  • Study the effects of cosmic rays on molecular structures
  • Explore the formation and implications of hydroxide cations
  • Investigate the role of UV light in radical formation
USEFUL FOR

Chemistry students, researchers in radiation effects, and professionals studying molecular interactions under high-energy conditions will benefit from this discussion.

bigplanet401
Messages
101
Reaction score
0

Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?

Homework Equations


The Attempt at a Solution



My knowledge of chemistry is very limited, and my guess is that it would be ionized:

<br /> e + H_2 O \rightarrow H^+ + OH + 2e<br />

Here, a high energy electron hits the molecule and releases 1 electron from the H atom, making it a cation. Two electrons appear in the products: 1 from the H along with the original electron.

If something like this were possible, then could a "hydroxide cation" be formed?

<br /> e + H_2 O \rightarrow H + OH^+ + 2e<br />

And if a photon strikes the molecule, how about

<br /> \gamma + H_2 O \rightarrow H_2 + O<br />

(Can water absorb photons?)

I am trying to understand how a covalently-bonded molecule "breaks up" when bombarded with cosmic rays, and would like to know if any of these examples (which contain such a molecule) are plausible. Thanks for your help!
 
Physics news on Phys.org
You are reducing water, so the reaction is simply H_2O+e^- \rightarrow \frac{1}{2}H_2+OH^-
You just can't go and cleave bonds that easily. And for the cosmic rays, I think that everybody can form radical, as many species does in UV light. (Cosmic rays are too powerful I suppose)
 
bigplanet401 said:

Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?

Also known as ionizing radiation. There is a lot of information on the web regarding ionizing radiation and it's effects on the water molecule.
 

Similar threads

  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
2
Views
3K
Replies
7
Views
2K
  • · Replies 34 ·
2
Replies
34
Views
5K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 1 ·
Replies
1
Views
5K
  • · Replies 17 ·
Replies
17
Views
2K
  • · Replies 7 ·
Replies
7
Views
15K
Replies
4
Views
4K