Ionizing a covalently-bonded molecule?

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  • Thread starter bigplanet401
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In summary, when a high energy electron or photon collides with a water molecule, it can cause ionization which leads to the formation of ions such as H^+ and OH^- as well as free radicals. This can result in the breaking of bonds within the molecule, leading to the formation of new compounds. The process is complex and can have various outcomes, but it is possible for a hydroxide cation to be formed as well as other products. The effects of cosmic rays on covalently-bonded molecules, like water, can also lead to the formation of radicals and other compounds. Further research is needed to fully understand the mechanisms involved.
  • #1
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Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?


Homework Equations





The Attempt at a Solution



My knowledge of chemistry is very limited, and my guess is that it would be ionized:

[tex]
e + H_2 O \rightarrow H^+ + OH + 2e
[/tex]

Here, a high energy electron hits the molecule and releases 1 electron from the H atom, making it a cation. Two electrons appear in the products: 1 from the H along with the original electron.

If something like this were possible, then could a "hydroxide cation" be formed?

[tex]
e + H_2 O \rightarrow H + OH^+ + 2e
[/tex]

And if a photon strikes the molecule, how about

[tex]
\gamma + H_2 O \rightarrow H_2 + O
[/tex]

(Can water absorb photons?)

I am trying to understand how a covalently-bonded molecule "breaks up" when bombarded with cosmic rays, and would like to know if any of these examples (which contain such a molecule) are plausible. Thanks for your help!
 
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  • #2
You are reducing water, so the reaction is simply [tex]H_2O+e^- \rightarrow \frac{1}{2}H_2+OH^-[/tex]
You just can't go and cleave bonds that easily. And for the cosmic rays, I think that everybody can form radical, as many species does in UV light. (Cosmic rays are too powerful I suppose)
 
  • #3
bigplanet401 said:

Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?

Also known as ionizing radiation. There is a lot of information on the web regarding ionizing radiation and it's effects on the water molecule.
 

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