Iron, Sulfur, and Hydrochloric Acid

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    Acid Iron sulfur
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Discussion Overview

The discussion centers around the reaction of hydrochloric acid with mixtures of iron and sulfur, specifically exploring why a heated mixture reacts while an unheated mixture does not. The scope includes chemical reaction mechanisms and the concept of activation energy.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant notes that hydrochloric acid reacts with a heated mixture of iron and sulfur but questions why it does not react with an unheated mixture, suggesting that no reaction occurred during a demonstration.
  • Another participant raises a general question about reactions that occur at elevated temperatures but not at lower temperatures, implying a broader principle may apply.
  • A third participant expresses confusion regarding the inquiry, indicating a lack of clarity in the question posed.
  • One participant suggests that many reactions are more likely to occur when reactants are heated, introducing the concept of activation energy as a key factor.
  • A later reply clarifies that the "heated mixture" refers to iron sulfides rather than elemental iron and sulfur, emphasizing that the properties and reactivities of compounds differ from their constituent elements.
  • This participant also notes the absence of vigorous gas evolution in the unheated mixture, suggesting that while a reaction may be occurring slowly, it is not readily observable at room temperature.

Areas of Agreement / Disagreement

Participants express differing levels of understanding and clarity regarding the inquiry. There is no consensus on the specifics of the reactions or the underlying principles, as some participants raise questions while others provide explanations.

Contextual Notes

The discussion does not resolve the assumptions regarding the nature of the mixtures or the specific chemical reactions involved. The role of temperature in influencing reaction rates remains a point of exploration.

Soaring Crane
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I know that hydrochloric acid reacts with a heated mixture of iron and sulfur, but why does it not react with an unheated mixture of iron and sulfur? (During a demonstration, I could see a soggy mixture of the powder and fillings in the acid, and I noticed nothing so I am assuming no reaction occurred. Is this correct?)

Thanks.
 
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I can attempt to answer this only in the general case. And the way I'll start is by asking a question : do you not know of any other reaction that works hot, but not cold ?
 
Er, I'm sorry but I don't understand what's being inquired . . . :confused:
 
Anyone?

Thanks.
 
This one's gotten far enough sideways.

Soaring Crane said:
I know that hydrochloric acid reacts with a heated mixture of iron and sulfur,

"... a heated mixture ..." is a student's way of saying "a mixture of iron and sulfur that has been heated." That is, HCl reacts with pyrite, marcasite, troilite, and however many other iron sulfides. The key point here is that the "heated mixture" is not iron, nor sulfur, and does not exhibit the chemical properties of either of the elements from which it was prepared.
but why does it not react with an unheated mixture of iron and sulfur? (During a demonstration, I could see a soggy mixture of the powder and fillings in the acid, and I noticed nothing so I am assuming no reaction occurred. Is this correct?)

You did not see any vigorous evolution of gas, therefore, no rapid reaction of acid with metal (it is proceding, but slowly at room temperature), nor did you see any other obvious signs of other chemical reactions that are occurring in the "soggy mixture." The point of the demonstration is that the compound, iron sulfide (I'm not going to hazard a guess which) has different properties and reactivities toward HCl than do the constituent elements.
 

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