Is an Ice/Water Mixture Preferred Over Pure Ice in the Crystallization Process?

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SUMMARY

The discussion centers on the advantages of using an ice/water mixture over pure ice in the crystallization process following gravity filtration. An ice/water bath effectively cools the filtrate to approximately 0°C, while pure ice or an ice-salt bath can achieve temperatures below 0°C. The primary benefit of the ice/water mixture is enhanced contact between the liquid and the flask, leading to more efficient cooling. In specific applications, such as distillation, an isopropanol-water ice bath is preferred to minimize corrosion of metal components.

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In the crystallization process after gravity filtration is carried out, a mixture of ice and water is sometimes used as a bath instead of just ice. I know that the ice/water bath can be used to cool the filtrate to around 0 C while just crushed ice or an ice-salt bath may cool the filtrate to below 0 C. An ice/water mixture instead of pure ice is used so that the solution does not ultimately freeze?? (Are there any examples where one is preferred over another?)

Thank you.
 
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It is usually because there is better contact between the liquid and the flask in an ice/water bath. An ice bath would only contact the flask in spots.
 
sometimes they add salts to the icewater bath to get it colder around -3C and the better efficency at cooling because more surface is contacted
it depends what application is used but the freezing is not usually a problem unless you have a pure liquid with a higher freezing point. in distillation sometimes they use an isopropanol water ice bath to slow the corrosion of metal parts and it gets very cold
 

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