Is electrolyte chemical consumed during alkaline water electrolysis?

AI Thread Summary
In alkaline water electrolysis, Potassium hydroxide or Sodium hydroxide is added to facilitate the process, but there is uncertainty about whether these chemicals are consumed and need replacement. For a DC current cell, it is suggested that potassium or sodium metal may be electroplated onto the electrodes, depending on cell voltage. In contrast, an AC current cell allows for cyclic plating and stripping of metals, preventing their consumption. The discussion also explores the potential of switching DC polarity to minimize electrode electroplating and maintain electrolyte chemistry. Overall, the efficiency of alkaline water electrolysis may be less favorable compared to PEM electrolysis, prompting considerations for optimizing the process.
Stormer
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In alkaline water electrolysis you add Potassium hydroxide, or Sodium hydroxide to the water you want to turn into hydrogen and oksygen. But is the Potassium hydroxide, or Sodium hydroxide consumed during electrolysis and needs to be replaced? Or do you just have to keep adding water as it is turned into hydrogen and oxygen?
 
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I expect for a DC current cell, collecting the gasses separately, the potassium metal or sodium metal would be electro-plated onto the electrode. That may depend on the cell voltage.
For an an AC current cell, collecting mixed gasses, the metals would not be consumed as they are cyclically plated onto, and then stripped off the electrodes.
 
Baluncore said:
potassium metal or sodium metal would be electro-plated onto the electrode
Are you certain? We're talking about an aqueous system
 
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Baluncore said:
I expect
Bystander said:
Are you certain?
No.
But reaction of the metal and water may be prevented by the voltage gradient at the polarised electrode surface.
Do you have a better answer?
 
Baluncore said:
I expect for a DC current cell, collecting the gasses separately, the potassium metal or sodium metal would be electro-plated onto the electrode. That may depend on the cell voltage.
For an an AC current cell, collecting mixed gasses, the metals would not be consumed as they are cyclically plated onto, and then stripped off the electrodes.
In that case alkaline water electrolysis would come out pretty bad compared to PEM electrolysis even with the higher cost of the materials in the PEM membranes.
Or maybe you can switch a DC alkaline elektrolyser polarity at regular intervals making a kind of low frequency switched AC and at the same time switching a valve to keep the oxygen and hydrogen in their separate output pipes? Just to avoid the electroplating of the electrodes, and the consumption of the electrolyte chemistry.
 
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Stormer said:
Just to avoid the electroplating of the electrodes, and the consumption of the electrolyte chemistry.
I think it is only necessary to momentarily remove the potential to recover the plated material. That suggests a pulsed, or a full-wave rectified AC supply will continuously recycle the metal hydroxide while keeping the gasses separate.
 

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