Is Hot Ice Possible Under High Pressure?

  • Context: Undergrad 
  • Thread starter Thread starter FallenApple
  • Start date Start date
  • Tags Tags
    Hot Ice
Click For Summary
SUMMARY

The discussion centers on the concept of "hot ice," which refers to the possibility of water transitioning into a solid state under high pressure while maintaining a higher temperature than conventional ice. It is established that water can exist in multiple phases, specifically Ice VI and Ice VII, when subjected to pressures between 200-400 MPa. The phase diagram illustrates the relationship between pressure and temperature, showing that water can freeze under high pressure without cooling down to 0°C. This phenomenon is attributed to the unique crystalline structures of ice that form under varying conditions.

PREREQUISITES
  • Understanding of phase diagrams and their significance in thermodynamics
  • Knowledge of water's unique properties, including its expansion upon freezing
  • Familiarity with high-pressure physics and its effects on molecular structures
  • Basic concepts of kinetic energy and temperature relationships
NEXT STEPS
  • Research the properties and phases of water ice, specifically Ice VI and Ice VII
  • Study phase diagrams in detail to understand pressure-temperature relationships
  • Explore high-pressure experimental techniques used in material science
  • Investigate the implications of water's behavior under extreme conditions in geological contexts, such as ringwoodite
USEFUL FOR

Scientists, physicists, and students interested in thermodynamics, material science, and the unique properties of water under varying pressure and temperature conditions.

FallenApple
Messages
564
Reaction score
61
So I've heard that increasing pressure in water would make the molecules more compact and then eventually become a solid. So it's possible to have hot ice.

But isn't it also true that as pressure increases, the temperature increases as well. For example, if I increase the force per volume, the average kinetic energy should increase because the force increased. So in hot ice, the kinetic energy should be higher, so how would it be in a solid form? Perhaps there is something I'm not understanding. Would it just be a vibrating solid?
 
Science news on Phys.org
If you compress something it gets hotter, but heat can radiate away.
You then have the compressed something in a denser state, but at it's original temperature
 
  • Like
Likes   Reactions: CWatters
FallenApple said:
So I've heard that increasing pressure in water would make the molecules more compact and then eventually become a solid. So it's possible to have hot ice.

Unlike most liquids water expands when it forms conventional ice but other forms of ice with different structures can exist that are smaller than water.

You can control the pressure and temperature of something independently. What happens is described in a phase diagram (graph of pressure vs temperature)..

Google found..

https://www.reddit.com/r/askscience...ter_is_compressed_enough_would_it_turn_solid/

You can learn about things like this by looking at a phase diagram for a substance.

2000px-Phase_diagram_of_water.svg.png

That red horizontal line is what water normally does. If the temperature goes down (move left on the line), water will eventually freeze. Freezing is at 0o C under 1atm of pressure (or 101.3 kPa). Duh.

What happens if you take liquid water and squish it instead? Will it turn solid? Just follow the liquid region up to higher pressures and the answer is yes (assuming while compressing it you're also keeping it at a steady temperature which might be difficult). How much pressure are we talking about? Well, look at the lines... looks like you need at least 200-400 MPa, or a few thousand times atmospheric pressure to do this!

You'll notice that water compressed to its 'freezing point' turns into either Ice VI or Ice VII. Most people don't realize that water ice has at least 15 phases! These phases are distinguished because the crystalline structure of the ice will be different in each phase. Pretty cool stuff!
 
instead of comparing it to ice, imagine it as instead going from water to gelatin to a solid form of gelatin. that's the best I can do to explain it without giving you a headache. you are correct with the fact that as it gets more compressed it would get warmer but the heat would radiate away eventually. leaving you with "hot" ice.
 
What about ringwoodite?
 

Similar threads

  • · Replies 10 ·
Replies
10
Views
2K
  • · Replies 5 ·
Replies
5
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 23 ·
Replies
23
Views
2K
  • · Replies 29 ·
Replies
29
Views
4K
  • · Replies 16 ·
Replies
16
Views
3K
  • · Replies 35 ·
2
Replies
35
Views
5K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 4 ·
Replies
4
Views
2K