cji, I tend to agree with you on conventional approaches but I like to think outside the box. For example, what about a nano-vortex? The laws of physics change with scale, what isn't possible in the macro world might be possible in the micro world. Perhaps we could imagine a MEMS (Micro Electric Mechanical Systems) device that would suck in air and form a microscopic tornado, maybe then the molecules would behave differently?
The reason I ask is I have this idea about an air breathing rocket propulsion system. In order for it to work you have to somehow get the oxygen out of the atmosphere without all the nitrogen, water, and CO2. The method of fractionating the air would have to be very efficient to serve this purpose. If anyone is interested in this idea you can look at the attachment.
Remember, it's just a concept. Which isn't even an idea. I suspect the complexity of it is too much toever be reduced to practice. But you can't blame me for thinking about it :^) Physics is fun.