Is Quantum Mechanics Truly Time-Reversal Symmetric?

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SUMMARY

The discussion centers on the time-reversal symmetry in quantum mechanics (QM), specifically addressing the implications of measurement and the collapse of the wave function. Standard QM exhibits time-reversal symmetry in its dynamics, represented by unitary operators, while the measurement process introduces irreversibility, violating this symmetry due to the second law of thermodynamics. The participants explore the potential for reformulating quantum theory to maintain time symmetry, particularly in equilibrium states, and the role of anti-unitary operators in this context. Key references include the paper linked by the original poster and established theories regarding the Hamiltonian and entropy in QM.

PREREQUISITES
  • Understanding of quantum mechanics fundamentals, including wave functions and state vectors.
  • Familiarity with the concepts of unitary and anti-unitary operators in quantum theory.
  • Knowledge of the second law of thermodynamics and its implications for irreversibility.
  • Basic comprehension of entropy and its role in quantum measurements.
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  • Research the role of anti-unitary operators in quantum mechanics, focusing on their implications for time-reversal symmetry.
  • Explore the concept of entropy in quantum systems and its relationship to measurement processes.
  • Investigate the potential reformulations of the second law of thermodynamics in a time-symmetric context.
  • Study the implications of the Hamiltonian in quantum mechanics, particularly regarding stability and time evolution.
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This discussion is beneficial for theoretical physicists, quantum mechanics researchers, and students interested in the foundational aspects of quantum theory, particularly those exploring the intersections of measurement, entropy, and time symmetry.

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What is it and why should it apply to qm?
I've bumped into a few interesting papers talking about time-reversal symmetry in QM (eg: https://arxiv.org/abs/1507.07745) but I can't seem to wrap my head around the concept.

1) What does it mean for one to say that standard QM isn't time-reversal symmetric? Does this have to do with the "collapse" post-measurement?

2) Why should we look for quantum theory that is time-reversal symmetric? Are the reasons empirical or theoretical?

Regarding 2), I found a passage on wikipedia that says: "In other words, time is said to be non-symmetric, or asymmetric, except for special equilibrium states when the second law of thermodynamics predicts the time symmetry to hold. However, quantum noninvasive measurements are predicted to violate time symmetry even in equilibrium, contrary to their classical counterparts,". Does this mean that these theorists are looking to modify QM such that time symmetry holds for these "equilibrium states"? The paper I cited, on the other hand, doesn't say anything about such equilibrium states.

Thanks in advance!

Edit: What role does an anti-unitary operator have to play in all this?
 
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Last first, do you mean non-unitary vs anti-unitary? Non-unitary operators can be used to represent dissipative and hence irreversible evolution.

To your main questions, there are two components to standard QM. The first is the dynamics which is expressed via unitary operators acting on the system description (wave function, "state" vector, or density operator). This is time reversal symmetric.

The second is the interpretation of the system description in terms of acts of observation. Observables are expressed as Hermitian operators, their available values being the eigenvalues. An act of observation is an irreversible process. One is amplifying the "signal" contained in one of the system's observables and that is a intrinsically thermodynamic process. The time asymmetry manifests in the "collapse" i.e. the projection onto the eigenspace of the observable contingent on the actual value observed. The magnitude of the projection relative to the prior description tells us the probability of observing that specific value via Born's formula.

The measurement process is not time symmetric due to the 2nd law of thermodynamics.

(Grandiose speculation warning!)
Now I believe it is possible to reformulate the 2nd law in a time symmetric fashion and I think that might be what the paper is about implicitly.

If you imagine that you sharply measure some system with a large numbers of components, say a box full of many hydrogen atoms, then you would write down a sharp description of the system at that time. The system would have entropy 0. If you then assert the system was coupled to a larger high entropy environment and unitarily evolve backward in time you would find the entropy of the description would increase as time devolves.
Keep in mind that entropy is not a substance or energy. It is a measure of how imprecisely we
We lose knowledge about both past and future systems relative to the present when we allow them to evolve/have evolved while coupled, however weakly, to the environment.
 
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Thanks for your response

jambaugh said:
The second is the interpretation of the system description in terms of acts of observation. Observables are expressed as Hermitian operators, their available values being the eigenvalues. An act of observation is an irreversible process. One is amplifying the "signal" contained in one of the system's observables and that is a intrinsically thermodynamic process. The time asymmetry manifests in the "collapse" i.e. the projection onto the eigenspace of the observable contingent on the actual value observed. The magnitude of the projection relative to the prior description tells us the probability of observing that specific value via Born's formula.

This is the part I don't quite get in the paper. What would a series of operations in T-symmetric quantum theory, say, state preparation and then measurement in the ##+t## direction look like in the ##-t## direction? And if indeed this lack of reversibility is due to thermodynamics, why would the authors feel the need to formulate a T-symmetric quantum theory?

Cheers.
 
jambaugh said:
Last first, ...

Love it! Only appropriate in a thread on time symmetry. :biggrin:
 
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jambaugh said:
(Grandiose speculation warning!)
Now I believe it is possible to reformulate the 2nd law in a time symmetric fashion and I think that might be what the paper is about implicitly.

If you imagine that you sharply measure some system with a large numbers of components, say a box full of many hydrogen atoms, then you would write down a sharp description of the system at that time. The system would have entropy 0. If you then assert the system was coupled to a larger high entropy environment and unitarily evolve backward in time you would find the entropy of the description would increase as time devolves.
Keep in mind that entropy is not a substance or energy. It is a measure of how imprecisely we
We lose knowledge about both past and future systems relative to the present when we allow them to evolve/have evolved while coupled, however weakly, to the environment.

I think it is fair to say that [Boltzmann] entropy increases in both time directions. A measurement would represent a local maximum of knowledge. That is not something normally considered (entropy to the past), but I have seen a few references in the literature over the years.
 
Time reversal symmetry is somewhat special. I've not followed the above quoted paper, which seems to claim something different to the well-established standard treatment of this symmetry, according to which standard QT is time-reversal invariant. So here I refer to the standard treatment, known since the very beginning of QT.

First of all one has to take into account that the Hamiltonian is a very special observable in QT since it defines the time evolution of the system. One conclusion is that a system can only be stable if the Hamiltonian is bounded from below, i.e., there should be a state (or maybe several degenerate states) of minimum energy.

The first important consequence of this is that you cannot ##\hat{H}## interpret as the canonical conjugate momentum of time and thus time is a "c-number"-parameter in quantum theory, labelling the causality order of events (as in classical physics too).

Now, as proven by Wigner, a single symmetry transformation can always be lifted to either a unitary or antiunitary transformation. For a review, see

https://doi.org/10.1063/1.1704188
If you have an entire continuous (e.g., as usual in physics even a Lie group) the symmetry transformations are necessarily unitary, while discrete symmetries may be antiunitary.

Now the Hamiltonian for a stable system is bounded from below, and since it generates time translations the time-reversal operator must act as
$$\hat{T}(\mathrm{i} \hat{H})\hat{T}^{\dagger}=-\mathrm{i} \hat{H}.$$
Thus, in order for ##\hat{H}## not flip sign, we must necessarily assume that ##\hat{T}## is anti-unitary rather than unitary.
 
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