I think you've got it all right and correct, just that the wording in post #1 was rather unfortunate.
With nowadays visualization possibilities it's almost a stone-age approach to put things in words, but let's do it anyway:
let's look in the blue plane of figure 2-26 (a) for the case ##\alpha \in [\pi/2, \pi]## where all the angles in our story are
[edit] I mean to say that all the angles are in that plane. Sorry for the ambiguity.
so the vertical line A
yz is in the yz plane and that plane is perpendicular to the x axis.
and as you can see the line from A
x to A (the green line) is parallel to that plane and therefore also perpendicular to the x axis. Hence my 90 ##^\circ##.
You of course in your post #1 meant to refer to the angle between ##\vec A## and ##\vec A_x## which as you can see is ##\pi-\alpha ## and thereby in the range 0 to 90##^\circ##.
Note that I forgot to draw the arrow above ##\vec A_x## and ##\vec A_{yz}##. Nobody is perfect, be we keep trying.
To be specific: in ##\vec A_x = A_x\, \hat\imath\ ##, ##\ A_x## is a number (negative for the alpha in the picture: ##A_x = |\vec A | \cos\alpha##