Is the Hydrogen Atom Ground State Wave Function Normalized?

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Homework Help Overview

The discussion revolves around the normalization of the ground state wave function for the electron in a hydrogen atom, represented mathematically. Participants are examining the conditions under which the wave function is considered normalized, referencing the integral of the square of the wave function over the appropriate domain.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the mathematical steps involved in integrating the wave function and question the validity of the original poster's integration approach. There are suggestions to reconsider the bounds of integration and the dimensionality of the problem, indicating a need for clarity on the use of spherical coordinates.

Discussion Status

Some participants have provided feedback on the integration process and pointed out potential errors in the original poster's calculations. There is an ongoing exploration of the correct approach to normalization, with no explicit consensus reached yet.

Contextual Notes

Participants note that the original integration bounds may not be appropriate for the radial coordinate and suggest that the normalization should be considered in three dimensions, which may affect the setup of the problem.

jg370
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Homework Statement



The ground state wave function for the electron in a hydrogen atom is:

[tex]\psi(r) = \frac{1}{\sqrt (\pi a_o^3)} e^\frac{-r}{a_o}[/tex]

where r is the radial coordinate of the electron and a_o is the Bohr radius.

Show that the wave function as given is normalized.


Homework Equations



Any wave function satisfying the following equation is said to be normalized:

[tex]\int_{-\infty}^{+\infty} |\psi|^2\dx = 1[/tex]


The Attempt at a Solution



Because the sum of all probabilities over all values of r must be 1,

[tex]\int_{-\infty}^{+\infty} (\frac{1}{\sqrt (\pi a_o^3)} e^\frac{-r}{a_o})^2 dr = \frac{1}{\pi a_o^3} \int_{-\infty}^{+\infty} e^\frac{-2r}{a_o^2} dr = 1[/tex]

Since the integral can be expressed as the sum of two integrals, we have,

[tex]\frac{1}{\pi a_o^3} \int_{-\infty}^{+\infty} e^\frac{-2r}{a_o^2} dr = \frac{2}{\pi a_o^3} \int_0^{+\infty} e^\frac{-2r}{a_o^2} dr = 1[/tex]

After integrating, I obtain,

[tex]\frac{1}{\pi a_o^3} = 1[/tex]

which is definitely incorrect. However, I do not see any other way to proceed. could someone give some assitance.

Thanks for your kind assistance

jg370
 
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you integrated wrong -
[itex]\int_0^{\infty} e^{-\frac{2r}{a_0^2}} dr = [-\frac{a_0^2}{2} e^{-\frac{2r}{a_0^2}]_0^{\infty}=\frac{a_0^2}{2}[/itex]

which gives [itex]\frac{1}{2 \pi a_0}=1[/itex]
 
the a_0 in your exponent shouldn't be squared, also the normalization condition says you should integrate over the bounds of your function. if r is the radial coordinate then how can it have a value of negative infinity? similarly your no longer normalizing in 1-d but 3D I recommend using spherical coordinates in which case your integral inherits a r^2 sin theta
 
Tks. I wil try again using spherical coordinates
 

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