PeterDonis said:
The Klein-Gordon equation is used in QFT, but there, as I said, the fields aren't numbers, they're operators, so it doesn't even make sense to ask whether they're real or complex numbers.
Schrodinger initially looked at the KG equation, but it had difficulties. From Wikipedia:
'The Klein–Gordon equation was first considered as a quantum wave equation by Erwin Schrödinger in his search for an equation describing de Broglie waves. The equation is found in his notebooks from late 1925, and he appears to have prepared a manuscript applying it to the hydrogen atom. Yet because it fails to take into account the electron's spin, the equation predicts the hydrogen atom's fine structure incorrectly, including overestimating the overall magnitude of the splitting pattern by a factor of 4n/2n − 1 for the n-th energy level.'
Due to this problem, in January 1926, Schrödinger submitted for publication a non-relativistic approximation that predicts the Bohr energy levels of hydrogen but without its fine structure.
Of course, once the cat was out of the bag, so to speak, the KG equation was soon discovered again. However, this time there was a more detailed analysis of its issues:
A new approach was required. Dirac had published his theory of the quantum EM field. He used the idea of expanding the field into its Fourier components and considers these components as harmonic oscillators. It is easy to quantise a harmonic oscillator (with its creation and annihilation operators), and the quantum theory of the EM field was born. So we had two views of quantum physics: a field view and a particle view. This was obviously a problem.
https://nicf.net/articles/qft-free-fields/
So the KG equation was reinterpreted as a field equation rather than a particle equation (leading to the misleading name "second quantisation"). The real reason is that, conceptually, quantum physics is simpler if everything is a field, and particles, like the photons of the EM field, are bundles in the field. This is the view of QFT. The field is modelled as creation and annihilation operators. The KG equation was written in this way and was found to describe spin-zero particles, which, of course, the electron is not. Also, lo and behold, the issues disappeared. The field is not an ordinary classical field, but rather mathematically described by operators.
From Ballentine, if we assume the axioms of ordinary QM and Galilean invariance, as shown in Chapter 3, Schrödinger's equation naturally follows. It should come as no surprise that if you use Lorentz invariance, you will run into problems, and indeed you do.
Thanks
Bill