Isobaric Process: Finding Q, E, W.

In summary, the problem involves finding the change in energy, Q, and W for an isobaric process of an ideal gas. To solve for W, use the ideal gas law to relate PΔV to ΔT, and be mindful of the sign convention for work.
  • #1
yaylee
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Homework Statement



n = 1.46 moles of ideal gas are heated isobarically (at constant pressure) from temperature To = 431 oC to temperature Tf = 1227 oC. Find: change in Energy, Q, W.

Homework Equations



Change in IE = Q + W
W (isobaric process) = P(vf-v1)

The Attempt at a Solution


change in IE = change in KE (because it is an ideal gas) = (3/2)nRT.
So, (3/2)(1.46)(8.314 x 10^-3)(1227-431) = 14.5 kJ (no issue here)

W = P(Vf-Vi), since it is an isobaric process.
However, how are you supposed to get the volumes of the initial and final state?

I tried pv = nRT, but am stuck with two unknowns. (Both Pressure, and Volume). Any suggestions? Many thanks in advance !
 
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  • #2
Hint: You don't need separate values for P and V. You only need the combination PΔV.
Can you relate PΔV to ΔT using the ideal gas law?

Also, be careful with signs. You wrote ΔIE = Q + W. So, W is work done on the system. Does PΔV represent work done on the system or work done by the system?
 

1. What is an isobaric process?

An isobaric process is a thermodynamic process in which the pressure of a system remains constant while its volume, temperature, and internal energy may change.

2. How do you find Q (heat) in an isobaric process?

To find Q in an isobaric process, you can use the equation Q = ΔH = PΔV, where ΔH is the change in enthalpy, P is the constant pressure, and ΔV is the change in volume.

3. How do you find E (internal energy) in an isobaric process?

To find E in an isobaric process, you can use the equation E = ΔH - PΔV, where ΔH is the change in enthalpy and PΔV is the work done by the system.

4. How do you find W (work) in an isobaric process?

To find W in an isobaric process, you can use the equation W = PΔV = -ΔE, where P is the constant pressure, ΔV is the change in volume, and ΔE is the change in internal energy.

5. What are some real-life examples of isobaric processes?

Some real-life examples of isobaric processes include boiling water in an open pot, heating a balloon, and constant pressure cooking in a pressure cooker.

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