The potential at node a with respect to the reference node depends entirely upon the polarity of the 4V source. The picture is a bit fuzzy around that source, but it appears that the "+/-" indicator shows "+" at the top. That would make node a +4V. It would also make the indicated answers incorrect.
If the 4V source polarity were reversed, then node a would be at potential -4V with respect to ground, and the given answers would then look good.