Laboratory Chemisry Question - Redox Reaction

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SUMMARY

The discussion centers on the ineffectiveness of using the redox reaction between Fe2+ and H2O2 to determine [Fe2+] in a solution due to the lack of a visible color change at the stoichiometric endpoint. Participants noted that both hydrogen peroxide and water are clear and colorless, making it difficult to visually detect the transition from Fe2+ to Fe3+. Additionally, the stability of hydrogen peroxide in acidic solutions was questioned, indicating potential complications in using this method for accurate measurements.

PREREQUISITES
  • Understanding of redox reactions and stoichiometry
  • Knowledge of the color properties of iron ions (Fe2+ and Fe3+)
  • Familiarity with instrumental methods for endpoint detection
  • Basic chemistry concepts related to hydrogen peroxide stability
NEXT STEPS
  • Research the color changes of Fe2+ and Fe3+ in various solutions
  • Learn about instrumental methods for endpoint detection in titrations
  • Investigate the stability of hydrogen peroxide in acidic environments
  • Explore alternative methods for determining [Fe2+] concentrations
USEFUL FOR

Chemistry students, laboratory technicians, and educators involved in analytical chemistry and redox reaction studies will benefit from this discussion.

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Homework Statement



1. Explain why the following chemical reaction would not be effective to determine [Fe2+] in a given solution.

Fe2+ (aq) + H2O2 (aq)-> Fe3+ (aq)+ H2O(l) | in acidic solution

Homework Equations


The Attempt at a Solution



Hello:

I am thinking that there may be a lack of colour change to indicate the stiochiometric endpoint of the redox reaction. I know that hydrogen peroxide and water are both clear and colourless in solution.

However, I do not know the colours of Fe2+ and Fe3+ in solution.

Thank you in advance!
 
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Endpoint detection can be done with some instrumental method, so it should be not a problem (although listing it won't hurt). However, what do you know about hydrogen peroxide stability?
 

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