Lightscribe graphene super capacitor reproduction

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SUMMARY

The forum discussion centers on reproducing Kaner and El-Kady's graphene-based electrochemical capacitors (ECs) using a lightscribe technique. The process involves reducing graphite oxide (GO) to laser-scribed graphene (LSG) and creating electrodes on heat-stabilized transparency film. Key challenges include selecting an appropriate electrolyte, with 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4) identified as a high-density option, and determining suitable separators and sealing methods for the capacitor cells. The discussion highlights that while EMIMBF4 is not feasible for home production, alternatives like a simple NaCl solution can be considered.

PREREQUISITES
  • Understanding of electrochemical capacitors (ECs)
  • Familiarity with laser-scribing techniques
  • Knowledge of materials science, specifically graphite oxide (GO) and laser-scribed graphene (LSG)
  • Basic chemistry skills related to electrolytes and ionic liquids
NEXT STEPS
  • Research the synthesis and properties of 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4)
  • Explore alternative electrolytes for graphene-based capacitors, such as sodium chloride (NaCl) solutions
  • Investigate suitable separator materials for solid-state electrochemical capacitors
  • Learn about methods for sealing and connecting graphene electrodes in series and parallel configurations
USEFUL FOR

This discussion is beneficial for materials scientists, electrochemists, hobbyists interested in capacitor technology, and anyone looking to reproduce advanced energy storage devices using graphene.

ecgoeken
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I am trying to reproduce Kaner and El-Kadys Graphene based electrochemical capacitors (ECs). The process reduces Graphite-oxide (GO) to laser-scribed graphene (LSG) using a lightscribe. I think I have figured out a way to produce the graphite-oxide from watching a couple of great videos on youtube. My plan is to laser printer transparency film as a backing because it has been heat stabilized, and coat it with GO suspended in water and allow it to dry onto the film thereby leaving a film of GO. Then I will put this into the lightscribe. This should give me the electrodes needed for the LSG-ECs. I am struggling with which electrolyte to use and what seperator to use. From what I can gather Kaner's team used a couple of different electrolytes with different associated energy and power densities. In one iteration he produced an all solid state cell that used a polymer as both separator and electrolyte. From what I can tell he used the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4) to achieve his highest densities. Does anyone know if it is possible to make this ionic liquid at home or if there is a similar liquid that would achieve similar densities? I am also curious if anyone has any ideas on the separator to use, how to seal the entire cell, and how to attach each graphene electrode together in order to put them in series and in parallel. I know its a lot, but I would really like to reproduce these capacitors and put them to use. Thanks for your help!
 
Physics news on Phys.org
Link to El-Kady, et al's paper:
https://science.sciencemag.org/content/335/6074/1326
Citation:
El-Kady et al,
Science 16 Mar 2012:
Vol. 335, Issue 6074, pp. 1326-1330
DOI: 10.1126/science.1216744

ecgoeken said:
Does anyone know if it is possible to make this ionic liquid at home or if there is a similar liquid that would achieve similar densities?
No, making EMIMBF4 is not really something an amateur chemist can do at home. I don't know if amateurs can purchase it. It's not a particularly dangerous chemical. I would suggest a simple NaCl solution to start.
 

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