Liouville, the second law and chaos

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Discussion Overview

The discussion revolves around the relationship between Liouville's theorem, which addresses the conservation of phase space volume, and the second law of thermodynamics, particularly in the context of chaos and coarse-graining. Participants explore theoretical implications and interpretations of these concepts, including subjective notions of entropy.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant references a paper by Michel Baranger that discusses how chaos can reconcile Liouville's theorem with the second law through the concept of coarse-graining, which leads to a larger effective volume.
  • Another participant mentions that the authors of the referenced article have likely considered the relationship between Liouville's theorem and the second law, suggesting their mathematical approach is complex.
  • Coarse-graining is identified by multiple participants as a standard explanation for the second law, though its subjective nature is questioned.
  • There is a discussion about whether the notion of entropy being subjective is comparable to renormalization, with some participants agreeing that it is a valid analogy.
  • One participant notes that chaos is usually associated with coarse-graining but acknowledges that a second law could arise from coarse-graining without chaos.
  • Participants share references to literature, including a book and a paper, to further explore the topic of coarse-graining and its implications.

Areas of Agreement / Disagreement

Participants express varying degrees of understanding regarding the subjective nature of entropy and the necessity of chaos in the context of Liouville's theorem and the second law. There is no clear consensus on these points, indicating ongoing debate and exploration.

Contextual Notes

Some participants highlight the complexity of the mathematical treatment of these concepts and the potential for differing interpretations based on the definitions used. The discussion includes references to specific figures and literature that may not be universally accessible or agreed upon.

Who May Find This Useful

This discussion may be of interest to those studying thermodynamics, statistical mechanics, chaos theory, or the philosophical implications of entropy and information theory.

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Demystifier said:
Yes, coarse-graining is the standard explanation of the second law.
See e.g. Fig. 3.1 in
http://www-physics.ucsd.edu/students/courses/spring2010/physics210a/LECTURES/210_COURSE.pdf
Great notes. But somehow I don't yet grasp the idea of the entropy of the second law being a subjective notion. Is this comparable with renormalization, where physical parameters depend on the energy scale one is looking at?and is Invoking chaos necessary in this coarse-graning picture of Liouville's theorem vs the 2nd law?
 
haushofer said:
But somehow I don't yet grasp the idea of the entropy of the second law being a subjective notion.
This is explained even in popular science books, such as
https://www.amazon.com/dp/9812832254/?tag=pfamazon01-20

In short, entropy counts the number of microscopic realizations of a given macroscopic state. But the notion of the "macroscopic" state is very subjective.

haushofer said:
Is this comparable with renormalization, where physical parameters depend on the energy scale one is looking at?
Yes, that's a good analogy.

haushofer said:
and is chaos necessary in this coarse-graning picture of Liouville's theorem vs the 2nd law?
It's usually associated with chaos, but not always. In principle, it is possible to have a second law due to coarse graining without chaos.
 
Last edited by a moderator:
Thanks. Your book recommendation seems curious. I've "The physics of information" by Bais and Farmer in my closet and will read up with this coarse graining.
 
haushofer said:
"The physics of information" by Bais and Farmer
My google search does no find such a book. Are you sure about the title and authors?
 
haushofer said:
Ah, it's a paper. :woot:
You said that it is in your closet, so I assumed that it is a book. Whenever possible, I like to keep papers as pdf's, not as papers in a literal sense. :biggrin:

Anyway, the paper seems great!

EDIT: Now I have realized that the paper is published as a chapter in the book "Philosophy of Information", which is a book that I already have.
 
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