Longitudinal acoustic phonons: why does the dielectric function vanish?

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SUMMARY

The discussion centers on the relationship between the zeros of the dielectric function and the frequency of longitudinal acoustic phonons, as presented in Kittel's "Introduction to Solid State Physics." Participants debate whether Kittel's assertion that \(\epsilon(\omega_L) = 0\) is adequately proven in the text. Physics Monkey clarifies that in the absence of free charge, longitudinal waves necessitate \(\epsilon = 0\), linking this to Maxwell's equations. The conversation also touches on the differences between optical and acoustic phonons, with references to Ashcroft and Mermin's work providing additional context.

PREREQUISITES
  • Understanding of dielectric functions and their significance in solid-state physics.
  • Familiarity with Maxwell's equations in the context of electromagnetic fields.
  • Knowledge of longitudinal and transverse wave properties in materials.
  • Basic concepts of phonons, particularly acoustic and optical types.
NEXT STEPS
  • Study the derivation of the dielectric function in solid-state physics, focusing on Kittel's "Introduction to Solid State Physics."
  • Examine Maxwell's equations in momentum space to understand their implications for wave propagation.
  • Explore the differences between acoustic and optical phonons in Ashcroft and Mermin's "Solid State Physics."
  • Investigate advanced treatments of phonon behavior in materials, referencing Fetter and Walecka's work.
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Physicists, solid-state researchers, and students seeking to deepen their understanding of phonon behavior and dielectric properties in materials.

FranzDiCoccio
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Hi everybody,

In chapter 10 of Kittel's "Introduction to Solid State Physics" it is said that the zeros of the dielectric functions determine the frequency of the longitudinal modes of oscillation, \epsilon(\omega_L) = 0, Eq. (17).
Am I missing something or this is actually an "unproved claim" as far as Kittel's book is concerned?
I mean, just below Eq (17), at page 276, there is a very short reference to depolarization, "to be discussed below". As far as I understand such a discussion is in the section "screening and phonons in metals" (page 286), where Eq. (17) is given for granted...

Hence, in summary, \epsilon(\omega_L) = 0 seems to me just a piece of information that Kittel gives us, without proving it. Or is it too obvious for proving?
Maybe I'm missing something... Sometimes one misses evident points when looking from a too short distance...
Has anyone any illuminating comment?

I have taken a look at more advanced textbooks, and, as far as I understand, it is a matter of poles and resonances..

Thanks a lot
 
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Hi Franz,

I don't think its obvious (and what is really?). One way to see the connection between zeros of the dielectric function and longitudinal waves is to consider a Maxwell equation in medium. Written in momentum space Gauss' law looks like k \cdot D = 0 or \epsilon k \cdot E = 0. What this equation tells you is that in the absence of "free charge" we must either have k\cdot E =0 or \epsilon = 0. Thus longitudinal waves k \cdot E \neq 0 require \epsilon = 0.

Hope this helps!
 
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Hi Physics Monkey,

and thanks a lot for replying! Your coment definitely helps.

Put in this form, Kittel's statement is still perhaps not obvious, but becomes quite intuitive, at least at a first sight. I wonder why Kittel didn't include such an illuminating comment based on simple Fourier analysis and vector calculus...

Anyway, this argument seems to suggest that what matters is transverse vs longitudinal.
But I suspect that optical vs acoustical has a role as well...

Indeed, I had found the argument you provide in the book by Ashcroft and Mermin (Ch. 27), and a similar one in Chapter 3 of Kittel's Quantum Theory of Solids. In both cases the subject is optical phonons, where one has a depolarization field.

Does this argument apply also to acoustic phonons? I do not see that. I'm asking because Kittel explicitly refers to acoustic phonons, at least in my copy of the 7th edition of his ItSSP book (page 286).
 
FranzDiCoccio said:
Anyway, this argument seems to suggest that what matters is transverse vs longitudinal.
Yes.
FranzDiCoccio said:
But I suspect that optical vs acoustical has a role as well...
Does this argument apply also to acoustic phonons? I do not see that. I'm asking because Kittel explicitly refers to acoustic phonons, at least in my copy of the 7th edition of his ItSSP book (page 286).
"optical vs acoustical" hasn't a role in "poles"...
Physics Monkey already made it clear enough.

As to referencing Kittel it depends :)))
17 equation in my case is: (see attachment)
 

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  • kittel-17.jpg
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Yes."optical vs acoustical" hasn't a role in "poles"...
Physics Monkey already made it clear enough.

Physics Monkey's argument is extremely clear to me. Actually so clear
that I'm surprised that, as far as I can see, it is nowhere to be found in a basic book like Kittel's
"Introduction to Solid State Physics". But I could have missed it..
Anyway, in other books, I find it only in connection with long wavelength optical modes, and the polarization field thereof.

I'll take a closer look to more advanced treatments.

As to referencing Kittel it depends :)))
17 equation in my case is: (see attachment)

I'm not sure I get that. Are you suggesting that switching to another book could be a wise choice?
Anyway I mentioned that I was referring to the 7th edition of Kittel ITSSP. Is your attachment from the same edition?

cheers :)
 
FranzDiCoccio said:
Physics Monkey's argument is extremely clear to me. Actually so clear
that I'm surprised that, as far as I can see, it is nowhere to be found in a basic book like Kittel's "Introduction to Solid State Physics". But I could have missed it.. Anyway, in other books, I find it only in connection with long wavelength optical modes, and the polarization field thereof. I'll take a closer look to more advanced treatments.
Excuse me, please. I live in Russia and I had never been outside former USSR. Russian old literature on this subject is rather huge (in russian) and contains the answer to your question. But after the cold war and after the greate criminal revolution in Russia we have very poor scientific literature in russian :(((
So, i think that this question had been solved many years ago and contemporary editors mechanically adopt it.
By the way, when was the first edition of Kittel book?
I like Kittel very much, especially for his "elementary" "Statistical mechanics".
May be you are more familiar with contemporary books. But Quantum Mechanics and EMF theory hardly changed since 1930 years, except some countable on fingers of one hand exclusions.
FranzDiCoccio said:
I'm not sure I get that. Are you suggesting that switching to another book could be a wise choice?
Anyway I mentioned that I was referring to the 7th edition of Kittel ITSSP. Is your attachment from the same edition?
cheers :)
I don't know the exact edition :)))
To my mind the first is the first forever especially love :)))

To get closer to the ground, i love V. Fock(the head of my department in Leningrad State University), Kittel, Haken, Dicke, Tamm (see Theory of Electricity with the answer to your question, he is the Nobel prize winner, once i have met with his son speaking about job, his son was the leader of the expedition to Everest), Davydov, Maslov, Arnold,... and i don't like very much Landau, Halatnikov and other pathological members of this club (except Migdal and some other members).

As a matter of fact, as a winner of schoolchildren competition in Moscow region in 1969 i received as a prize the book (among other 15 books) "Theory of superconductivity" of 1960 edition (i was 16 then). It was a translation to russian all significant works on this subject: Frohlich, BCS work, Cooper review, Valatin,...

Is it a mystery?

It's my handbook now :)))

Old books are closer to the physical meaning. New books are closer to a business success.

May i ask the admins do not delete this message?
 
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Minich,

thanks for sharing your thoughts.

As I say, I'll look into other books to understand this thing better. I think precious hints will come from Ashcroft&Mermin, Fetter&Walecka and the like.
I'll try some of the books you suggest, assuming I'm able to find them.

Thanks again.

-F
 

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