Lowering of Vapour Pressure - a C.P ?

In summary, the conversation discusses whether lowering of vapour pressure is a colligative property and if the proof provided by one person is correct. It is determined that lowering of vapour pressure is indeed a colligative property, but there is a distinction between relative lowering of vapour pressure and just lowering of vapour pressure. The conversation also asks for recommendations for a free reaction simulation software.
  • #1
zorro
1,384
0
Is lowering of vapour pressure a colligative property?

I tried proving this and found it to be true.

Pa = Poaχa, where a=solvent and b=solute

Substituting χa=1-χb and some rearranging, we get

Poa-Pa=Poaχb

As Poa is constant for a given liquid at a given temperature, lowering of vapour pressure (LHS) is directly proportional to the no. of moles of solute provided the solution is very dilute.

Is my proof correct?
 
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  • #2
Hi
your proof is correct
right lowering of vapour pressure really is a colligative property
 
  • #3
But my book says that Relative lowering of vapour pressure is a colligative property but lowering of vapour pressure is not a colligative property.
 
  • #4
hi,

can anyone tell me where i can get a free reaction simulation software, like aspen plus.

thanks.
 
  • #5


Yes, your proof is correct. Lowering of vapour pressure is indeed a colligative property, meaning it is dependent on the number of particles present in a solution rather than the identity of those particles. This is because the presence of solute particles reduces the number of solvent particles available to escape into the gas phase, resulting in a lower vapour pressure. Your equation accurately represents this relationship and your proof supports the concept of colligative properties. Well done!
 

1. What is the concept of lowering of vapour pressure?

The concept of lowering of vapour pressure, also known as colligative property, refers to the phenomenon in which the vapour pressure of a liquid decreases when a non-volatile solute is added to it.

2. How does the addition of a solute affect the vapour pressure of a liquid?

The presence of a solute in a liquid reduces the number of solvent molecules available at the surface, thereby decreasing the vapour pressure. This is because the solute particles disrupt the intermolecular forces between the solvent molecules, making it harder for them to escape into the gas phase.

3. What is the relationship between the lowering of vapour pressure and the concentration of solute?

The lowering of vapour pressure is directly proportional to the concentration of solute present in the solution. This means that the greater the concentration of solute, the lower the vapour pressure will be.

4. How does temperature affect the lowering of vapour pressure?

As with most colligative properties, the lowering of vapour pressure is also affected by temperature. An increase in temperature causes an increase in the kinetic energy of the solvent molecules, making it easier for them to escape into the gas phase. This results in a higher vapour pressure and a smaller decrease in vapour pressure due to the presence of solute.

5. What are some real-life applications of the lowering of vapour pressure?

The concept of lowering of vapour pressure is used in various industrial processes, such as distillation and freeze drying. It is also utilized in everyday life, for example, in antifreeze solutions for cars and in the preservation of food items by adding salt or sugar.

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