Lowering of Vapour Pressure - a C.P ?

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Discussion Overview

The discussion revolves around whether lowering of vapour pressure qualifies as a colligative property, with participants exploring definitions and interpretations of related concepts in physical chemistry.

Discussion Character

  • Debate/contested

Main Points Raised

  • One participant presents a mathematical proof suggesting that lowering of vapour pressure is a colligative property, based on the relationship between the vapour pressures of the solvent and the solute.
  • Another participant agrees with the proof, affirming that lowering of vapour pressure is indeed a colligative property.
  • A third participant references a textbook that differentiates between relative lowering of vapour pressure as a colligative property, while stating that lowering of vapour pressure itself is not considered a colligative property.
  • A separate inquiry is made about obtaining free reaction simulation software, indicating a shift in focus from the main topic of discussion.

Areas of Agreement / Disagreement

There is disagreement among participants regarding the classification of lowering of vapour pressure as a colligative property, with some asserting it is while others reference a source that claims it is not.

Contextual Notes

The discussion highlights differing interpretations of colligative properties and the reliance on specific definitions from textbooks, which may not align with all participants' views.

zorro
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Is lowering of vapour pressure a colligative property?

I tried proving this and found it to be true.

Pa = Poaχa, where a=solvent and b=solute

Substituting χa=1-χb and some rearranging, we get

Poa-Pa=Poaχb

As Poa is constant for a given liquid at a given temperature, lowering of vapour pressure (LHS) is directly proportional to the no. of moles of solute provided the solution is very dilute.

Is my proof correct?
 
Chemistry news on Phys.org
Hi
your proof is correct
right lowering of vapour pressure really is a colligative property
 
But my book says that Relative lowering of vapour pressure is a colligative property but lowering of vapour pressure is not a colligative property.
 
hi,

can anyone tell me where i can get a free reaction simulation software, like aspen plus.

thanks.
 

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