Material balance- purge cycle help

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The discussion focuses on calculating the flow rate and composition of a purge stream in a hydrogen reduction process involving Fe2O3. The reaction produces metallic iron and water, with unreacted hydrogen being recycled. The challenge arises from the need to limit CO2 impurities in the reactor feed to 2.8%, given that the fresh hydrogen feed contains 1.1% CO2. The solution involves establishing a CO2 balance and determining the flow rate of the purge stream, which is calculated to be 23.76 kmol/h, with a composition of 3.1% CO2 and 96.9% H2.

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simon.23
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Hydrogen is used to reduce 2.3 tonne per hour, Fe2O3 to metallic iron according to the reaction

Fe_{2}O_{3} + 3H_{2} = 2Fe + 3H_{2}O

The water is condensed and the unreacted hydrogen is recycled (see diagram attached). Because the hydrogen in the fresh feed contains 1.1% CO2 as an impurity, some of the unreacted hydrogen must be purged. Calculate the flow rate and the composition of the purge stream required to limit the CO2 in the reactor feed to 2.8% if the ratio of recycle to fresh feed is 11:2 on a molar basis.
MW(Fe) = 55.85, MW(H) = 1.01, MW(O) = 16.00.


I am really struggling to get to grips with this question, ( struggling with material balance overall!)

I can do dimple material balance however for things with a recycle stream or purge stream, really confuses me.

I have the solution which I will post up, but I still don't get 'why' it is solved in this manner. I would really appreciated it, if someone explains to me why. Or if you have simpler way of working the flow rate of the purge stream?

thank you,
 

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SOLUTION;

CO2- Balance;


0.011x + y = 6.5x (0.028)

y = 0.0171x in the recycle stream.

\frac{0.0171x}{5.5x} \times 100 = 3.1 \% of CO2 in purge stream,
100 - 3.1 = 96.9 % H2 in purge stream. Flow rate of purge:

CO2 BALANCE-

0.011x = 0.031p , x = \frac{0.031p}{0.011}

H2 Balance-
0.989x = 43.204 + 0.969p

2.787p = 43.204 + 0.969p

p = 23.76 kmol h^{-1}

Firstly, I don't get why the flow rate of the purge stream is equal to the flow rate of the fresh feed stream?

Surely it won't be the same, as some CO2 is being recycled? Your also loosing water and Fe iron, from the fresh fee, you have two outputs, so surely the flow rate of the fresh feed would be more than the flow rate of the purge stream, so you can't set them equal to each other?
 

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