Minimal of free energy equation

  • Thread starter Thread starter finchesarecool
  • Start date Start date
  • Tags Tags
    Energy Free energy
Join the discussion
Registration is free. Start your own thread to ask a follow-up.
1 reply · 1K views
finchesarecool
Messages
1
Reaction score
0

Homework Statement


Show that the free energy, F=SUM(E_i*p_i)+T*SUM(p_i*ln(p_i)) is minimal when p_i=e^(-E_i/T)/SUM(e^(-E_i/T))

Where E is energy, T is temperature

Homework Equations


Nothing really

The Attempt at a Solution


So if I just try and find the derivative of the force I arrive at something along the lines of p_i=e^((-E_i/T)-1).
I'm assuming I'm supposed to use some constraints to show that the entropy is fixed but I'm not sure how to go about doing that.
 
Physics news on Phys.org
Hi. Note that F is not a force but the Helmholtz free energy defined as F = U–TS;
Also note that you do have a minimum when pi is proportional to exp(–1–Ei/T) as you vary F and set δF = 0, but pi are probabilities and therefore they need to be normalized to 1...