Most probable speed of aluminium atoms

Click For Summary
SUMMARY

The most probable speed (vmp) of aluminium atoms at 1173K can be calculated using the formula vmp = √(2kT/m). In the discussion, the molar mass of aluminium is given as 0.0270 kg/mol, leading to an incorrect calculation of vmp as 1.1 x 10^-9 m/s. The error arises from using the molar mass instead of the mass of an individual aluminium atom. To correct this, one must divide the molar mass by Avogadro's constant (NA) to obtain the mass per atom or alternatively use the gas constant (R) instead of the Boltzmann constant (k).

PREREQUISITES
  • Understanding of the ideal gas law and kinetic theory of gases
  • Familiarity with Boltzmann constant (k) and gas constant (R)
  • Knowledge of Avogadro's constant (NA)
  • Basic algebra for manipulating equations
NEXT STEPS
  • Calculate the mass of an individual aluminium atom using the molar mass and Avogadro's constant
  • Learn about the relationship between temperature and molecular speed in gases
  • Explore the implications of kinetic theory in real-world applications
  • Investigate the differences between using Boltzmann constant and gas constant in calculations
USEFUL FOR

Students studying thermodynamics, physicists, and chemists interested in atomic behavior at high temperatures.

Bugsy23
Messages
24
Reaction score
0

Homework Statement



Aluminium atoms at 1173K enter a vacuum chamber. Calculate the most probable speed for the atoms.

Homework Equations



vmp=\sqrt{}(2kT/m)

The Attempt at a Solution



The molar mass of aluminium is 0.0270kg mol^-1, so
vmp=\sqrt{}(2*1.381*10^-23JK^-1)*1173K/0.0270kg mol^-1=1.1*10^-9ms^-1

Which is a really tiny quantity and it seems unrealistic that particles at such a high temperature would move that slowly. I've used SI units though so I can't see where I would have gone wrong. Any help would be appreciated. Thanks
 
Physics news on Phys.org
Bugsy23 said:
The molar mass of aluminium is 0.0270kg mol^-1, so
vmp=\sqrt{}(2*1.381*10^-23JK^-1)*1173K/0.0270kg mol^-1=1.1*10^-9ms^-1
You're using the molar mass combined with Boltzmann constant. But that doesn't make sense. You need the mass of an individual molecule (in this case an individual aluminum atom) if you want to use Boltzmann constant. (You can do this by dividing the molar mass by Avogadro constant NA to find the mass per individual molecule [in this case atom].)

Alternatively, you can stick with the molar mass and substitute Boltzmann constant k with the gas constant R, since k = R/NA.
 
Last edited:
Thanks, I've got it now
 

Similar threads

  • · Replies 8 ·
Replies
8
Views
4K
  • · Replies 13 ·
Replies
13
Views
1K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 5 ·
Replies
5
Views
6K
  • · Replies 8 ·
Replies
8
Views
5K
  • · Replies 10 ·
Replies
10
Views
5K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 15 ·
Replies
15
Views
37K
  • · Replies 8 ·
Replies
8
Views
8K
  • · Replies 2 ·
Replies
2
Views
5K