Nitrates and Nitrites with FeSO4 + CH3COOH

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SUMMARY

The discussion centers on the identification of nitrites (NO2-) using a reaction with freshly prepared iron(II) sulfate (FeSO4) and acetic acid (CH3COOH). Participants conclude that acetic acid is not a suitable substitute for sulfuric acid (H2SO4) in the brown ring test for nitrites, as it lacks the necessary strength to facilitate the reaction. The consensus is that the proposed reaction with acetic acid is invalid, and that concentrated sulfuric acid is essential for accurate detection of nitrites.

PREREQUISITES
  • Understanding of the brown ring test for nitrate detection.
  • Knowledge of chemical reactions involving FeSO4 and acids.
  • Familiarity with the properties of nitrites (NO2-) and nitrates (NO3-).
  • Basic principles of acid strength and its role in chemical reactions.
NEXT STEPS
  • Research the brown ring test for nitrate detection using FeSO4 and H2SO4.
  • Study the chemical properties and reactions of nitrites (NO2-) in aqueous solutions.
  • Investigate alternative methods for detecting nitrites in laboratory settings.
  • Examine the role of acid strength in facilitating chemical reactions.
USEFUL FOR

Chemistry students, laboratory technicians, and educators interested in chemical analysis and the detection of nitrites and nitrates.

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Homework Statement


I know that NO3- can be separately identify using newly made FeSO4 + H2SO4 using the brown ring test.
The problem is can we identify NO2- using newly made FeSO4 + CH3COOH? Replacing H2SO4 with CH3COOH?

Homework Equations


NO2-(aq) + FeSO4(aq) + CH3COOH(aq)\Rightarrow [A Brown Circle]?
or is this equation invalid?

The Attempt at a Solution


Nothing being attempted! :(
 
Last edited:
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NO2- or NO3-, you are inconsistent.

If NO3- try to find out what is the reaction involved.
 
Last edited:
Its NO2- is the problem. I've never learn such a reaction using Acetic acid to identify NO2- and a paper says you can't but I got it from a friend who says that using Acetic acid can identify NO2-.
 
I find it rather unlikely. While NO2- can interfere, test in general requires concentrated sulfuric acid, I doubt acetic acid is strong enough.
 
Yeah, I believe it too. So may I have the final conclusion as Acetic acid does nothing regarding detection of NO2-? I've never heard such a test too!
 
That's what I expect, but I have learned long to not assume everything I expect is true.
 

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