No covalent bond formation due to repulsion

Click For Summary
SUMMARY

Covalent bond formation can be hindered by repulsive forces, particularly in cases like the helium dimer ion He22+, which is isoelectronic with H2 and possesses a bond order of 1. Despite this bond order, the electrostatic repulsion between the two helium nuclei prevents stable bond formation. In contrast, the He2 molecule, while having zero bond order, is not primarily influenced by repulsive forces but rather by weak dispersion forces. Understanding these interactions is crucial in the study of molecular stability.

PREREQUISITES
  • Understanding of covalent bonding principles
  • Familiarity with bond order concepts
  • Knowledge of electrostatic forces in chemistry
  • Basic comprehension of molecular interactions, including dispersion forces
NEXT STEPS
  • Research the concept of bond order in molecular orbital theory
  • Study the properties and stability of helium dimers and their ions
  • Explore the role of electrostatic repulsion in molecular stability
  • Investigate dispersion forces and their impact on weakly bound systems
USEFUL FOR

Chemistry students, molecular physicists, and researchers interested in molecular bonding and stability dynamics.

Maria Malik
Messages
1
Reaction score
0
Hi,
I want to ask , is there any example in chemistry when during covalent bond formation the repulsive forces dominate and no bond is formed.
Thanks
 
Chemistry news on Phys.org
It's tough to know exactly what you mean. Plenty of diatomics have zero bond order (He2, for example), but I'm not sure I'd call the cause of that a "repulsive force." In fact, the helium dimer is weakly bound by dispersion forces. The closest thing I can think to what you're asking is a case like He22+, which is isoelectronic with H2, so it has a bond order of 1, but it is unstable because the two nuclei repel each other electrostatically.
 

Similar threads

  • · Replies 34 ·
2
Replies
34
Views
5K
  • · Replies 5 ·
Replies
5
Views
3K
Replies
14
Views
3K
Replies
6
Views
3K
  • · Replies 12 ·
Replies
12
Views
4K
Replies
3
Views
2K
Replies
18
Views
3K
  • · Replies 12 ·
Replies
12
Views
13K
Replies
4
Views
2K
  • · Replies 7 ·
Replies
7
Views
5K