Oxidation Numbers: Fe203+3CO to 2Fe+3CO2

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SUMMARY

The discussion focuses on the oxidation and reduction processes in the reaction Fe2O3 + 3CO → 2Fe + 3CO2. It is established that iron (Fe) is reduced as it gains electrons, while carbon (C) is oxidized as it loses electrons. The oxidation states are clarified, with oxygen consistently having an oxidation number of -2. The conversation emphasizes the importance of understanding oxidation numbers, which may differ from the valency indicated in the periodic table.

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By using oxidation numbers can someone show me what is oxidised and reduced

Fe203+3co->2Fe+3co2
 
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markosheehan said:
By using oxidation numbers can someone show me what is oxidised and reduced

Fe203+3co->2Fe+3co2

Hi Marko,

Making the ion forms explicit, we have:
$$
{Fe^{3+}}_2{0^{2-}}_3+3C^{2+}O^{2-}\to 2Fe+3C^{4+}{O^{2-}}_2
$$
So $Fe$ gains electrons and as such it is reduced.
And $C$ loses electrons, meaning it is oxidized.
 
I like Serena said:
Hi Marko,

Making the ion forms explicit, we have:
$$
{Fe^{3+}}_2{0^{2-}}_3+3C^{2+}O^{2-}\to 2Fe+3C^{4+}{O^{2-}}_2
$$
So $Fe$ gains electrons and as such it is reduced.
And $C$ loses electrons, meaning it is oxidized.

thanks
I usually go to the periodic table and look at the elements valency and then i take this as the oxidation number. this is not always correct though?
for example carbon has a valency of 4 but in the above equation it is 2+.
so you go off the ones you know like oxygen is always -2 and the oxidation number of a compound must always equal zero.
 
markosheehan said:
thanks
I usually go to the periodic table and look at the elements valency and then i take this as the oxidation number. this is not always correct though?
for example carbon has a valency of 4 but in the above equation it is 2+.
so you go off the ones you know like oxygen is always -2 and the oxidation number of a compound must always equal zero.

Yes, in compounds oxygen is always -2.
The metals (that are oxidized) usually have more than one oxidation number, and the valency doesn't even have to be one of them (copper for example).
 

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