Oxygen and mercury in a tube problem

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Homework Help Overview

The problem involves a tube containing oxygen gas and a column of mercury, with specific conditions regarding temperature and pressure. The scenario describes the behavior of the gas when the tube is flipped and heated, leading to a shift in the mercury column.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • Participants discuss the application of the ideal gas law and the relationship between pressure, volume, and temperature. There are questions about the pressure contributions from the mercury and atmospheric pressure, and how these relate to the gas pressure in the tube.

Discussion Status

Participants are exploring different interpretations of the pressure relationships in the system. Some have offered clarifications regarding the pressure contributions, while others express confusion about the implications of the tube being sealed at one end.

Contextual Notes

There is an indication of missing information regarding the calculation of initial gas pressure, and participants are grappling with the implications of the tube's configuration on the pressure equations.

Rugile
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Homework Statement


We have a tube with the top end open and the bottom end closed. There is some oxygen gas in the tube and on top of the oxygen there is 10 cm high column of mercury. The initial temperature is 20oC. Then the tube is flipped over and heated to 40oC. The column of mercury shifts by h = 8cm. What was the initial height of column of the gas if the atmospheric pressure is 105 Pa?

Homework Equations


Ideal gas law

The Attempt at a Solution


We can assume that the gas is ideal, from which we know that ##\frac{pV}{T} = const## thus ##\frac{p_0 V_0}{T_0} = \frac{p_1 V_1}{T_1}##. When we flip the tube over we also know that ##p_{ox} + p_{merc} = p_a##, where pox is oxygen pressure, pmerc is mercury pressure, and pa is atmospheric pressure. Also, we can state that ##V_1 = V_0 + Sh##, ##Sh_1 = Sh_0 + Sh##, thus we can rewrite the equation: ##\frac{p_0 S h_0}{T_0} = \frac{(p_a - p_{merc}) S (h_0 + h)}{T_1} => \frac{p_0 h_0}{T_0} = \frac{(p_a - p_{merc}) (h_0 + h)}{T_1}##. The only additional unknown here is p0, which I don't know how to calculate. I was thinking of using the equation ##p_0 V_0 = \frac{m}{M}RT_0##, but I don't have enough information to solve that equation for p0. Any ideas?
 
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Initial condition: capillary containing oxygen confined by 10 cm Hg column,
Rugile said:
10 cm high column of mercury.
open to atmosphere.
 
So do you mean that ##p_a = p_{merc} + p_0##? But what about the fact that the bottom end is sealed?
 
Bottom end.
 
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Sooo, the pressure of the gas is caused by the atmospheric pressure and mercury, thus ##p_0 = p_{merc} + p_a## instead? I'm confused
 
Rugile said:
pressure of the gas is caused by the atmospheric pressure and mercury
Very good.
 
Thank you for the help!
 

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