Partial derivatives in thermodynamics

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SUMMARY

The discussion focuses on the application of partial derivatives in thermodynamics, specifically in the context of multivariate calculus. The user highlights the need for understanding how to differentiate functions of multiple variables that are interdependent, such as in the expression for chemical potential, μ = - (∂U/∂S)_{N,V} (∂S/∂N)_{U,V}. The conversation emphasizes the importance of formal theorems related to partial derivatives and suggests consulting thermodynamics textbooks that cover these concepts. A resource link to Chapter 2 of a thermodynamics textbook is provided for further study.

PREREQUISITES
  • Understanding of multivariate calculus
  • Familiarity with thermodynamic concepts
  • Knowledge of partial derivatives and their applications
  • Basic grasp of functions of multiple variables
NEXT STEPS
  • Study the application of partial derivatives in thermodynamics
  • Review thermodynamic textbooks that cover partial derivatives
  • Explore the mathematical foundations of multivariable calculus
  • Investigate formal theorems related to partial derivatives
USEFUL FOR

Students and professionals in physics, particularly those studying thermodynamics, as well as mathematicians interested in the application of multivariable calculus in physical systems.

maxBrunsfeld
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in basic multivariate calculus, i never learned about differentiating functions of multiple variables which are also functions of each other. i.e.

[itex]\frac{d}{d x_1} \left[ f(x_1, x_2, x_3) \right][/itex]

where [itex]x_1 = g(x_2, x_3)[/itex]

studying thermodynamics right now, I'm encountering into expressions like

[itex]\mu = - \left(\frac{\partial U}{\partial S} \right)_{N,V} \left( \frac{\partial S}{\partial N} \right)_{U,V}[/itex]

where some particular variables are held fixed, but others are not. I'm wondering if there are formal theorems relating to partial derivatives like these or if you guys have any knowledge specifically relating to them.
 
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maxBrunsfeld said:
i'm wondering if there are formal theorems relating to partial derivatives like these

All the thermodynamics textbooks that I've seen, spend some time discussing them early on.

If yours doesn't, you might try downloading Chapter 2 from

http://www.astro.uvic.ca/~tatum/thermod.html

which I found by doing a Google search for "partial derivatives in thermodynamics".
 
thank you. that's exactly the kind of thing i was looking for. sorry if that was so easy to find that it didn't warrant asking the forum.
 

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