Phenol and FeCl3 Reaction: Formation of Violet Complex

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SUMMARY

The reaction between phenol (PhOH) and iron(III) chloride (FeCl3) results in the formation of a violet complex, specifically iron(III) phenolate, represented by the chemical equation FeCl3 + 3PhOH ----> Fe(O-Ph)3. This reaction is commonly known as the iron chloride test for phenolic compounds. The formation of the violet complex serves as a qualitative indicator for the presence of phenol groups in a sample.

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  • Chemical structure of phenol
  • Understanding of coordination chemistry
  • Knowledge of iron(III) chloride properties
  • Familiarity with colorimetric tests in organic chemistry
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  • Study the mechanism of phenol and FeCl3 reaction
  • Explore other colorimetric tests for phenolic compounds
  • Research the applications of iron(III) phenolate in analytical chemistry
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Chemistry students, organic chemists, laboratory technicians, and anyone involved in qualitative analysis of phenolic compounds.

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When phenol reacts with FeCl3, a violet complex will be formed. What is the name of the violet complex and what is the chemical equation for this reaction? I've tried to search it from the internet but I couldn't find the equation.
 
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FeCl3 + 3PhOH ----> Fe(O-Ph)3

it's the iron chloride test for phenol groups :smile:.

as for the name, i don't know off hand :wink:.
 

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