Powder XRD FCC spirals explanation

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Discussion Overview

The discussion revolves around the interpretation of spirals in powder X-ray diffraction (XRD) patterns, specifically in relation to face-centered cubic (FCC) lattice structures. Participants explore the significance of these spirals in determining lattice parameters and the underlying reasons for their shape and orientation.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant questions the reason for the spirals in the FCC lattice vectors, particularly why their minima align with the vertical axis.
  • Another participant explains that the spirals are used to find the lattice parameter by examining the polar angle where experimental data intersects with the spirals.
  • A participant suggests that the spirals may arise from the variation of the lattice parameter as a function of the polar angle.
  • There is a suggestion that the spirals could simply represent the spanning of the lattice constant.

Areas of Agreement / Disagreement

The discussion remains unresolved, with multiple competing views on the origin and significance of the spirals in the context of FCC lattices.

Contextual Notes

Participants express uncertainty regarding the relationship between the polar angle and the resulting spiral shape, as well as the implications for lattice parameter determination.

mohammed.omar
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Hello All,

I've been reading about XRD and found this picture online:
http://en.wikipedia.org/wiki/File:Aluminumpowderpattern.png

My question, which might be due to the lack of background as I'm an ECE guy, is why are the FCC lattice vectors depicted of Spirals whose minima lie on the vertical axis?
 
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The spirals are calculated to help find the lattice parameter of the sample under investigation.

The lattice parameter of the FCC lattice is changed as function of the polar angle. You look for the polar angle where the experimental data (circles, not spirals) cross the spirals - hopefully all at once. In the image this is indicated by the blue line.

I would think that these days a computer is able to find lattice parameters without such visual aids. But the papers cited are surprisingly recent.
 
Thanks M Quack,

So as the polar angle is increased the distance from the different planes changes and that is why we get a Spiral? If tihs is the case then why do they all have minima at the vertical axis?
 
Or these spirals just come from spanning the lattice constant?
 
spanning the lattice constant.
 
Thanks a lot M Quack
 

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