Principle Quantum Number - Transition

In summary, the transition from [4,3,0,1/2] to [4,2,1,-1/2] is allowed for the hydrogen atom according to the selection rules. However, there is no change in energy involved since \Delta n = 0. This may seem unusual, but it is possible for slight variations in energy within the same n state.
  • #1
cpmiller
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Homework Statement


Is the following transition allowed?

[4,3,0,1/2] -> [4,2,1, -1/2]

If so, find the energy involved and whether the photon is absorbed or emitted for the hydrogen atom.

Homework Equations



Selection rules for allowed transitions:
[tex]\Delta[/tex]n = anything
[tex]\Delta[/tex]l =[tex]\pm[/tex]1
[tex]\Delta[/tex]ml = 0 or [tex]\pm[/tex]1

The Attempt at a Solution



[tex]\Delta[/tex] n = 4-4 = 0
[tex]\Delta[/tex] l = 3-2 = 1
[tex]\Delta[/tex]ml = 0-1= -1

So all of the transitions are allowed, but it doesn't quite make sense to me.

There is no energy involved, because [tex]\Delta[/tex] n = 0, which means that this electron just suddenly spontaneously decided to be in a different configuration, can it do that?

(I also checked and it looks like both of the states are allowed...)

Can it do that, am I missing something?

Thanks for your help!
 
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  • #2
Your reasoning makes sense, the transition does appear to be allowed.

While the Bohr theory predicts the same energies, in reality the energies will be slightly different. Does your textbook or lecture notes say anything about energies of different l-states within the same n?
 

FAQ: Principle Quantum Number - Transition

What is the principle quantum number?

The principle quantum number, denoted by the letter "n", is a numerical value that represents the energy level of an electron in an atom. It determines the size and energy of an electron's orbital.

How does the principle quantum number relate to electron transitions?

The principle quantum number determines the energy difference between two energy levels, which is necessary for an electron to transition from one level to another. As the principle quantum number increases, the energy levels become closer together, making transitions between them easier.

What is the significance of transitions in atoms?

Transitions in atoms are important because they involve the movement of electrons from one energy level to another. This movement of electrons is responsible for the emission or absorption of energy in the form of light, which is essential for many chemical and physical processes in our world.

How many possible transitions are there for a given principle quantum number?

For a given principle quantum number "n", there are n possible transitions from one energy level to another. For example, if n=3, there are 3 possible transitions: 3 to 2, 3 to 1, and 3 to 0.

Can an electron transition to a higher energy level without absorbing energy?

No, an electron cannot transition to a higher energy level without absorbing energy. This is because transitions between energy levels require a specific amount of energy, which must be absorbed by the electron. Without this energy, the transition cannot occur.

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