Proper material for electrolytic cell?

  • Thread starter Thread starter mesa
  • Start date Start date
  • Tags Tags
    Cell Material
Click For Summary

Discussion Overview

The discussion revolves around the selection of materials for the cathode and anode in an electrolytic cell designed for recovering silver from waste fix solutions in photo labs. Participants explore various options that are not platinum and consider their effectiveness and availability.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants suggest that stainless steel is a good material for the cathode/anode, citing its effectiveness in the electrolysis of water.
  • Others express uncertainty about the suitability of stainless steel specifically for recovering silver.
  • One participant proposes that using silver itself could be a viable option due to its inertness in many applications, with the caveat that it may dissolve and reappear on the cathode.
  • Another participant acknowledges the potential of using silver but notes the challenges related to its cost and availability, particularly in the form of plates on campus.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the best material for the cathode/anode, with multiple competing views regarding the use of stainless steel versus silver remaining unresolved.

Contextual Notes

There are limitations regarding the assumptions about material effectiveness and availability, as well as the specific requirements for recovering silver from the waste solution.

mesa
Gold Member
Messages
694
Reaction score
36
We are considering recovering the silver out of our waste fix solution from the photo labs on campus.

What is the best (reasonably acquired) material (as in non-platinum) for the cathode/anode?
 
Chemistry news on Phys.org
For electrolysis of water stainless steel is very good, but I don't know about recovering silver.
 
kevin_tee said:
For electrolysis of water stainless steel is very good, but I don't know about recovering silver.

Stainless seems to be the best bang for the buck for this as well. Anyone else have something to add or does this seem like the most reasonable choice?
 
I wonder if silver itself would not do the trick. It is inert enough for many applications, and in case it dissolves it will just reappear on the cathode.
 
Borek said:
I wonder if silver itself would not do the trick. It is inert enough for many applications, and in case it dissolves it will just reappear on the cathode.

Silver would probably work and we could reverse the cathode/anode configuration to keep the plates 'even' but the material is expensive and could be difficult to find in plates, as in it is likely not available on campus in on of our scrap piles :)
 

Similar threads

Replies
4
Views
3K
  • · Replies 16 ·
Replies
16
Views
6K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 13 ·
Replies
13
Views
6K
  • · Replies 5 ·
Replies
5
Views
13K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 26 ·
Replies
26
Views
4K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 2 ·
Replies
2
Views
4K