QM: Commuting the Hamiltonian with position

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SUMMARY

The discussion centers on the commutation of the Hamiltonian operator, defined as H = p²/(2m) + V(x), with the position operator x in quantum mechanics. The derived commutator is [H,x] = -iħ/m * p, where p represents the momentum operator. Participants clarify that the presence of the derivative operator d/dx does not render the commutator zero, as d/dx does not commute with x. Furthermore, they emphasize that expectation values are taken for operators, reinforcing the interpretation of these values as averages of measurements on identically prepared quantum systems.

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Niles
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Homework Statement


Hi all.

I am commuting the Hamiltonian (H = p2/(2m) + V(x)) with position. This is what I get:

<br /> [H,x] = -\frac{i\hbar}{m}p, <br />

where p is the momentum operator. But here's my question: The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?

Because my trouble is that I have to take the expectation value of the above commutator, and how does it make sense to take the expectation value of an operator?

I hope you can shed some light on this. Thanks in advance.Niles.
 
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Niles said:
The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?
Why would it mean that? d/dx doesn't commute with x.

Niles said:
how does it make sense to take the expectation value of an operator?
Operators are the only things you ever take expectation values of in QM, so why wouldn't it make sense? The interpretation is that the expectation value tells you the average of a large number of measurements of the operator performed on identically prepared systems.
 
Niles said:
The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?


First, thanks for replying. What I mean is that we have a d/dx just "hanging" in the air, i.e.:

<br /> [H,x] = -\frac{i\hbar}{m}\frac{\hbar}{i}\frac{d}{dx}.<br />

The d/dx works on a constant ("1", I guess?), so that's why I think that it might be zero. But you say it is not?

Fredrik said:
Operators are the only things you ever take expectation values of in QM

Ok, that's comforting to know. That at least takes care of problem #2.

Thanks in advance.
 
Last edited:
Niles said:
<br /> [H,x] = -\frac{i\hbar}{m}\frac{\hbar}{i}\frac{d}{dx}.<br />

The d/dx works on a constant ("1", I guess?), so that's why I think that it might be zero. But you say it is not?
The d/dx does not work on a constant (necessarily). I suppose you could say that it is just hanging in the air. Remember, this is QM, and so observables are operators. What about H? Is H=V(x) because the Laplacian is working on a constant? No; it is also an operator. x is an operator, too, but we treat it like a regular number when we work in the configuration basis (as you are doing), which is the eigenbasis of x, so you can replace the operator x with its eigenvalue. If it makes you feel more comfortable, work with the "matrix elements":

<br /> \int{}dx\ \psi_1^*(x)[H,x]\psi_2(x)=-\frac{\hbar^2}{m}\int{}dx\ \psi_1^*(x)\frac{d\psi_2(x)}{dx}<br />

The only reason it would work on a constant is if a constant could solve the Schroedinger equation.
 
Great, thanks to both of you for taking the time to help me.
 

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