QM: Commuting the Hamiltonian with position

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Homework Help Overview

The discussion revolves around the commutation of the Hamiltonian operator with the position operator in quantum mechanics. The original poster is exploring the implications of their derived commutator and how it relates to taking expectation values of operators.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to understand whether the presence of the derivative operator in the momentum operator implies that the commutator is zero. They express confusion about taking the expectation value of an operator.
  • Some participants question the assumption that the commutator could be zero and clarify the nature of operators in quantum mechanics.
  • Others suggest considering the role of operators and their action on wave functions, emphasizing that operators are essential for expectation values.

Discussion Status

The discussion is active, with participants providing insights into the nature of operators and their implications in quantum mechanics. Clarifications regarding the expectation values and the behavior of operators are being explored, but no consensus has been reached on the original poster's specific question about the commutator.

Contextual Notes

The original poster's inquiry is framed within the context of quantum mechanics, specifically regarding the properties of operators and their mathematical treatment. There is an underlying assumption about the nature of the momentum operator and its implications for the commutation relation.

Niles
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Homework Statement


Hi all.

I am commuting the Hamiltonian (H = p2/(2m) + V(x)) with position. This is what I get:

<br /> [H,x] = -\frac{i\hbar}{m}p, <br />

where p is the momentum operator. But here's my question: The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?

Because my trouble is that I have to take the expectation value of the above commutator, and how does it make sense to take the expectation value of an operator?

I hope you can shed some light on this. Thanks in advance.Niles.
 
Last edited:
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Niles said:
The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?
Why would it mean that? d/dx doesn't commute with x.

Niles said:
how does it make sense to take the expectation value of an operator?
Operators are the only things you ever take expectation values of in QM, so why wouldn't it make sense? The interpretation is that the expectation value tells you the average of a large number of measurements of the operator performed on identically prepared systems.
 
Niles said:
The momentum-operator contains d/dx, so does this mean that the commutator is zero, or do I leave it as I have derived it above?


First, thanks for replying. What I mean is that we have a d/dx just "hanging" in the air, i.e.:

<br /> [H,x] = -\frac{i\hbar}{m}\frac{\hbar}{i}\frac{d}{dx}.<br />

The d/dx works on a constant ("1", I guess?), so that's why I think that it might be zero. But you say it is not?

Fredrik said:
Operators are the only things you ever take expectation values of in QM

Ok, that's comforting to know. That at least takes care of problem #2.

Thanks in advance.
 
Last edited:
Niles said:
<br /> [H,x] = -\frac{i\hbar}{m}\frac{\hbar}{i}\frac{d}{dx}.<br />

The d/dx works on a constant ("1", I guess?), so that's why I think that it might be zero. But you say it is not?
The d/dx does not work on a constant (necessarily). I suppose you could say that it is just hanging in the air. Remember, this is QM, and so observables are operators. What about H? Is H=V(x) because the Laplacian is working on a constant? No; it is also an operator. x is an operator, too, but we treat it like a regular number when we work in the configuration basis (as you are doing), which is the eigenbasis of x, so you can replace the operator x with its eigenvalue. If it makes you feel more comfortable, work with the "matrix elements":

<br /> \int{}dx\ \psi_1^*(x)[H,x]\psi_2(x)=-\frac{\hbar^2}{m}\int{}dx\ \psi_1^*(x)\frac{d\psi_2(x)}{dx}<br />

The only reason it would work on a constant is if a constant could solve the Schroedinger equation.
 
Great, thanks to both of you for taking the time to help me.
 

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