Quantum analog of Boltzmann entropy?

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Discussion Overview

The discussion revolves around the concept of entropy in statistical physics, specifically exploring whether there exists a quantum analog of Boltzmann entropy. Participants examine the distinctions between Boltzmann entropy, Gibbs entropy, and von Neumann entropy, as well as their applications in both equilibrium and non-equilibrium contexts.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants propose that Gibbs entropy, also known as Shannon entropy in information theory, serves as a general concept, while Boltzmann entropy is a specific application to the microcanonical ensemble in thermal equilibrium.
  • Others argue that Boltzmann entropy can be defined outside of equilibrium, highlighting that Boltzmann and Gibbs entropy differ in such contexts.
  • A participant mentions that the quantum analog of Boltzmann entropy may involve counting states in a manner similar to Planck, Einstein, Fermi, and Dirac, while neglecting higher-order correlations.
  • Concerns are raised about the generality of Boltzmann entropy, with some asserting that it relies on a one-particle distribution function, while Gibbs entropy is viewed as more general.
  • Another participant points out that the authors of a referenced paper apply Boltzmann entropy in a way that may not be limited to one-particle distributions, suggesting a broader scope in their analysis.
  • Some participants discuss the implications of using Boltzmann versus Gibbs entropy, particularly in relation to the nature of probability distributions in quantum physics.
  • There is mention of the conceptual difficulties in classical statistical mechanics compared to quantum statistical physics, with a preference expressed for starting from Shannon-Jaynes-von Neumann entropy.
  • Discussions include the relevance of Liouville's theorem and the definition of Boltzmann entropy in terms of microscopic trajectories and macroscopic states.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the existence or definition of a quantum analog of Boltzmann entropy. Multiple competing views are presented regarding the generality and applicability of Boltzmann and Gibbs entropy in various contexts.

Contextual Notes

Participants note limitations in definitions and assumptions regarding the application of Boltzmann and Gibbs entropy, particularly in non-equilibrium scenarios and the treatment of correlations.

  • #31
It depends on what you mean by "observer". If you mean a human being, taking note of measurement results, it's most probably irrelevant. What you have to take into account sometimes is of course the interaction between the measured object and the measurement device.
 
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  • #32
By observer do not mean humans, which I think I declared many times. It's thinking it's "humans" that are the root of the confusion.

I mean the observer=agent = the part of the universe in which the inference of the remainder takes place - ie the part that distinguishes, counts and records events at the input that interface to the rest of the world.

In your example, when considering QM or QFT in colliders etc (not talking about unification of gravity) the "observer" is IMO, ALL the macroscopic environment! This is essentially also as I see it what Bohr meant. Ie. the set of all possible classical pointers etc or what you call it. Or if we talk about special relatiivity, then the obvious generalisation is that the "observable" become the above modulo the poincare transformations. Ie the classical environment forms an equivalence class. The whole lab, including all also all it's computational power! But this is also why THIS observer is a fiction, because it's an asymptotic "superobserver". This is exactly why we do not consider THIS "observer" as part of the interaction beyond the idealised preparattion-detection.

The generealisation of this is what I look for, but the normal notion of above "observer" will be recovered when the "agent" becomes dominant. The generalization I think is they key to make progress on the open isuses (unification without finetuning, and QG). When you also try to do this generalisation both the ontology and the epistemolgoy is important. Both "extremes" are otherwise missing something.

/Fredrik
 
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  • #33
Why don't you simply talk it measurement device?
 
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  • #34
vanhees71 said:
Why don't you simply talk it measurement device?
Because then people tend to think of something described from ther perspective of another measurement device. Ie. If you think the "detector" is the measurement device, this detector is still described from the rest of the macroscopic world, meaning there is another measurement device further out.

I think the distinction is that the agent is supposed to be described from the inside, which makes it a bit subjective. But the objectibvity is supposedly restored - along with more explanatory power - when one ponders how these interacting agents change as they communicate. Ie. we expect there to be for example at a set of agents or "observers" that are related via a symmetry transformation. But WHICH symmetry transformation? I think there is more explanations begind WHICH symmetries that are manifested in nature.

Then we have no grip of this if we describe the measurement device in the external traditional way, becauase there is an implicit choice of background that causes problems and finetuning questions.

/Fredrik
 
  • #35
Detectors are usually all there is relevant in the sense of measuring a particle. They are indeed big enough to be treated classically. There is nothing more subjective in the quantum description of Nature than in the classical description. The question, which symmetries (or regularities, describable by mathematics) are manifested in Nature has to be found out by observation and model building in close interdepency. It's at the deepest level what the entire endeavor of the natural sciences is about.
 
  • #36
vanhees71 said:
Detectors are usually all there is relevant in the sense of measuring a particle. They are indeed big enough to be treated classically. There is nothing more subjective in the quantum description of Nature than in the classical description.
Yes, I agree. And the subjectivity of the macroscopic domain is neglectable when it comes to small subsystems.

But problems appear when the "quantum part" contains parts that are treated both as quantum, and as part of the classical part (ie. part of the observer). And even worse when one considers gravity.

vanhees71 said:
The question, which symmetries (or regularities, describable by mathematics) are manifested in Nature has to be found out by observation and model building in close interdepency. It's at the deepest level what the entire endeavor of the natural sciences is about.
The problem I see is this: Unless we find a more coherent theory that connects or relates the effective theories (much better than today that is), then - in principle - the scientific findings and the inference for any given experimental setup, has to be done independently for each observation or energy scale. This is not "wrong" but it leaves us with a patchwork of effective theories, with a bunch of experimentally tuned parameters, without the slightest clue how they are related.

Can we improve this situation? How?

/Fredrik
 
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  • #38
Fra said:
By observer do not mean humans, which I think I declared many times. It's thinking it's "humans" that are the root of the confusion.

I mean the observer=agent = the part of the universe in which the inference of the remainder takes place - ie the part that distinguishes, counts and records events at the input that interface to the rest of the world.
Can a dog be an agent?
 
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  • #39
Demystifier said:
Can a dog be an agent?
What I meant is that I that a agent/observer doesn't need to be human - not that can't be human, or a dog for that matter. I only want to get away from those associating "epistemology" as a human phenomena.

The generalized physical concept I imagine is more how one part of the universe can "learn" via interactions, about other parts of the universe. The parts does not need to have brains. As I see it, an agent needs at least a structure for encoding information, and a way to process this information and respond to input. This processing in my vision does not imply brains, or computers, it can be "natural processes". Ultimaltey, the instruction set would somehow be related to the laws of physics, but at the same time these laws are subject to constant evolution.

So, sure a dog can be an agent, or a a molecule can also be an agent in the general sense. In the ordinary sense of observer a la Bohr, where it's essential the macroscopic(or "classical") environment that is the observer, then the role of the human is that it can _control_ the laboratory and the procedure of preparation and detectors, electronics etc. In this sense the physicist at least in principle have control, and access to the whole macroscopic environment, at least to the extent technology and economy allows. The exeprimental uncertainty there is, is IMO a manifestation of the ambigousness of the macroscopic observer still. This uncertainty would be larger if the negineers at LHC were dogs, but the principles are the same.

Surely a dog can't do this, and dogs would not produce QED or QCD. Those "theories" are certainly human inventions.

So what I entertain at this point are "toy models" of primordal observers, which is like the simplest possible "agents" one can imagine. It's nowhere near a dog or a molecule in complexity, it's imaginary things that I envision would perhaps been dominating in some TOE era in early big bang. One idea is similar to string theory, where my "interpretation" of string theory, would be this: the "string" is the mathematical description of a primordal observer or a living "measure". The modes of the string represents it's way of encoding information. But the problem is that the strings also lives in a background spacetime, whose dynamics is poorly understood still it seems. The various dualities in string theory in my mind, corresponds to agents different "internal recodings" or alternative representations, which also gives different dynamics. But one would need to understand the interaction between strings, and systems of strings, to understand how the background is selected. Then one can imagine largers objects constructed by strings interacting and consider the evolutionary pressure of making transition to other bakgrounds (via dualities). But I have realise this is not how string theorists think, i can't recall ahving seen one paper in this direction. So I have chosen another path.

/Fredrik
 
  • #40
So, I'm hesitant to post this because I get a somewhat crack potty feeling to the book (however, he actually does reference some of your papers in the more "normal" section [i.e section 1.5.2 he references https://arxiv.org/abs/quant-ph/0305131]), but I'm not sure if that's because my Bohmian mechanics principles are weak (I only know the basic of how they apply the Hamilton-Jacobi equations), but with that being said...

I stumbled upon this book https://www.amazon.com/dp/9813227974/?tag=pfamazon01-20 in my search for a book to learn this theory.

At the start of chapter 2, he states:
"##S_Q=-\frac{1}{2} \ln \rho##
where ##\rho## is the probability density (describing the space-temporal distribution of an ensemble of particles, namely the density of particles in the element of volume ##d^3 x## around a point ##\vec{x}## at time ##t## )associated with the wave function ##\psi(\vec{x}, t)## of an individual physical system. In the entropic version of Bohmian quantum mechanics, the space-temporal distribution of the ensemble of particles describing the individual physical system under consideration is assumed to generate a modification, a sort of deformation of the background space characterized by the quantity given by equation (2.1). On the basis of equation (2.1), it is plausible to make a parallelism with the standard definition of entropy given by the Boltzmann law, in other words equation (2.1) may be considered indeed as the quantum counterpart of a Boltzmann-type law. In the light of its relation with the wave function, the quantity given by equation (2.1) can be appropriately defined as "quantum entropy". The quantum entropy (2.1) can be interpreted as the physical parameter that, in the quantum domain, measures the degree of order and chaos of the vacuum - a storage of virtual trajectories supplying optimal ones for particle movement - which supports the density ##\rho## describing the space-temporal distribution of the ensemble of particles associated with the wave function under consideration."

So, the issues I have is that everything he references in this part is... his own articles, which IMO isn't THAT big of an issue, it just gets more suspicious because I can't find the journals/papers. But, I'll post this for you, and let you be the judge.

[BTW, in case anyone is interested, I ended up going with https://www.amazon.com/dp/0521485436/?tag=pfamazon01-20 but just need to actual take time and study the chapters in depth, but it is a nicely written book so far IMO.]
 
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  • #41
@romsofia Holland is a classic, pretty sure anyone working in BM read it. While for the 1st book you quoted, you need to check the table of references (bibliography). Does it contain only known books and articles in peer-reviewed journals? Does it include references published by the book's author? Making sure of these does not, however, exclude the possibility that the book is full of crackpot ideas, or simply wrong statements. Today, anyone can publish a book. WS, Springer, and others will not ensure that the board of editors accepts only correct manuscripts.
 
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  • #42
dextercioby said:
Does it contain onltly known books and articles in the peer-reviewed journals? Does it include references published by the book's author?
Exactly the issue I ran into. One of his own papers (that he references a lot to justify the relation in the boltzmann entropy) comes from "D. Fiscaletti, “Perspectives of Bohm’s quantum potential towards a geometrodynamic interpretation of quantum physics. A critical survey”, Reviews in Theoretical Science 1, 2, 103–144 (2013)". However, this journal seems to be gone (and predatory?).

In fact, the only reason I decided to go ahead and post is because the book's author heavily uses OP's work, and even goes as far to dub his work as "Nikolic's approach" throughout the book. So, if anyone could be a proper judge, I'd guess it'd be from somehow who wrote the papers that influenced a lot of this book.
 
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  • #43
Sorry, for me publishing in a predatory journal is akin to uploading to vixra, because you can't get an endorsement to upload it to arxiv. @Demystifier Is this book by a certain Fiscaletti author known to you? Care to make some comments on it? Thanks!
 
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  • #44
romsofia said:
and even goes as far to dub his work as "Nikolic's approach" throughout the book.
It refers to my older works, but my approach has significantly changed in the meantime. My current view of Bohmian mechanics is best represented by the article in my signature, and more recently by https://arxiv.org/abs/2205.05986 where the last section describes how my views changed over time.
 
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