Quantum Chemistry and ground-state energy

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SUMMARY

The ground state energy of helium, when ignoring interelectronic repulsion, is calculated as eight times the ground state energy of hydrogen, denoted as EHe = 8EH. The corresponding wavefunction for helium is represented as ΨHe(r1, r2) = ΨH(r1H(r2), where ΨH is the hydrogen atom's ground state wavefunction. It is crucial to note that the total wavefunction must be antisymmetric due to the fermionic nature of electrons, which can be achieved by assigning opposite spin labels to the electrons.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly wavefunctions and Hamiltonians.
  • Familiarity with the Schrödinger equation and eigenfunctions.
  • Knowledge of spherical polar coordinates and the Laplacian operator.
  • Basic concepts of fermions and antisymmetry in quantum systems.
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  • Learn about the implications of antisymmetry in wavefunctions for identical fermions.
  • Explore the concept of electron correlation and its effects on ground state energy calculations.
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Homework Statement


If we were to ignore the interelectronic repulsion in helium, what would be it's ground state energy and wave function?


Homework Equations


I have created my ground state wave function \psi for 1s:

\psi = (1/\sqrt{}\pi)(z/a)3/2(e-zr/a)

The operator is the laplacian, in spherical polar coordinates.

The Attempt at a Solution



So the energy of the two particles is the hamiltonian operating on \psi,
and I should get an eigen function out which would be the energy for one of the two particles.
Using the laplacian operator I got:

E = [(-\hbar 2/2m)(1/\sqrt{}\pi)(z/a)3/2](z2/a2 e-zr/a - 2z/ar e-zr/a) + V(r)\psi

For the energy of the one particle. My problem is,
that this isn't an eigen function of the laplacian, and I've managed to hit a brick wall.
I'm completely stumped on what I could do, any help would be greatly appreciated!
 
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Blamo_slamo said:
If we were to ignore the interelectronic repulsion in helium, what would be it's ground state energy and wave function?
It might help to start by writing out the Hamiltonian. Ignoring the electron-electron repulsion term gives:
$$H = -\frac{\hbar^2}{2m}(\nabla^2_{\mathbf{r}_1}+\nabla^2_{\mathbf{r}_2}) -\frac{Ze^2}{4\pi \varepsilon_0 |\mathbf{r}_1-\mathbf{R}|}-\frac{Ze^2}{4\pi \varepsilon_0 |\mathbf{r}_2-\mathbf{R}|}$$
But hopefully you'll see this is just a Hamiltonian for two isolated hydrogen atoms. Couple that with the fact that ##Z_{He}=2Z_{H}## and you get that the ground state energy for each electron is ##E_{He} = 4E_H##. So the total ground state energy (for 2 electrons) is ##E_{He} = 8E_H## and the wavefunction is just ##\Psi_{He}(\mathbf{r}_1,\mathbf{r}_2) = \Psi_H(\mathbf{r}_1)\Psi_H(\mathbf{r}_2)##, where ##\Psi_H## is the ground state wavefunction for the hydrogen atom.

EDIT: one quick note, since the electrons are fermions, the total wavefunction must be antisymmetric with respect to exchange of ##\mathbf{r}_1## and ##\mathbf{r}_2##. Obviously, our ground state helium wavefunction above is not. However, if we attach spin labels to the electrons, then we can get back antisymmetry as long as the electrons have opposite spins.
 
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