Questions about a Hydrogen Economy; Scientific American

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The discussion centers on the concept of a "hydrogen economy," highlighting the misconception that hydrogen serves as a direct energy source like fossil fuels. Participants emphasize that hydrogen production requires more energy than it yields, often relying on fossil fuels or coal, which raises environmental concerns. The potential for nuclear energy to contribute to cleaner hydrogen production is noted as a preferable alternative. There is a consensus that while hydrogen can be an energy carrier, significant advancements in production technology and infrastructure are necessary for it to be a viable solution. Overall, the dialogue reflects skepticism about the feasibility of transitioning to a hydrogen economy without addressing underlying energy production challenges.
  • #91
zoobyshoe said:
I actually sent them an e-mail asking about the temperature it takes to change the NaOH to NaH, but it was returned to me as undeliverable. Have they already gone out of business?


I sent an email Today to :
matt@powerball.net

I too got the message returned, but for the following reason:

The users mailfolder is over the allowed quota (size). (#5.2.2)

Now, this may indicate that the company is out-of-business; or it may indicate that operation is temporarily suspended; or that "matt" is on vacation; that he is no longer with them; that he doesn't check his mail often; or that he gets a great number of emails, etc.

I might also add that I sent one to "Powerball" about a month age, which was apparently received by them, but never answered. I shall try "Thundervolt". Maybe they can tell us something about whether Powerball is still around, and if so, how to contact them.
 
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  • #92
I like the powerballs. I had a look at the page that explains the small standing system that is manufactured for them.

They have a page explaining that any of the light metals might be used to make them. I wonder which has the least dangerous aqueous form?

I do think they underestimate the inconvenience of distributing them compared to fossil fuels. Nothing compares to the fuel distribution pipelines.

I did some reading on the NaH itself. It is pretty dangerous stuff. Just coming into contact with moist air will start it generating hydrogen, which can catch fire. The fire has to be smothered, can't use water for that of course, and the NaH will continue to produce hydrogen so long as the original moisture is present.

Trucking them around would require the design of an arrangement where they would be prevented from abrading each others plastic coating off. That could be done many ways but in all cases you couldn't just pile them on top of each other in a situation where the weight of the top ones bore down on the lower ones. Better to be inspired by the notion of shipping eggs than anything else. For all the same reasons you can't have them spilling out onto the highway, abrading their coating off, if the truck overturns on a slippery road in a rainstorm. Some kind of double-hulled carrying compartment with shock absorbing material between the hulls comes to mind as what would be needed.
 
  • #93
More on Powerball

There's a little bit more at:

http://www.isecorp.com/powerball_tank.htm
 
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  • #94
Powerball coatings

I think the covering shell for the Powerball is more than just a coating. At least as I understand, the liquid NaH is injected into the shells, hardened and then welded shut. (Actually, they describe it both as coating and injecting and welding within a two paragraph span.) They also say that the Powerballs are then tested. This may also be suggested by the fact that a hydraulically operated knife mechanism is needed to split open the balls, as needed in the tank. If this is true, however, it means that recycling the polyethylene shell will be somewhat more of a concern. It would suggest however, that the Powerball is at least as safe in a car/truck as a tank of gasoline.

I also notice that they are now testing Lithium and Lithium Hydride for use in Powerballs. These promise considerably more energy content, per gallon, than Sodium Powerballs - - and more potential for problems in case of an accident. The cost will probably also be considerably higher. (Aircraft maybe?)
 
  • #95
Kenneth Mann said:
I think the covering shell for the Powerball is more than just a coating. At least as I understand, the liquid NaH is injected into the shells, hardened and then welded shut. (Actually, they describe it both as coating and injecting and welding within a two paragraph span.)
They describe it in a couple places as a "briquetting" process. The powder is mechanically compressed into the ball shape first, then the coating is added. I don't see how they could do it by injection. It seems the liquid NaH would have to be much hotter than polyethelene could withstand.
They also say that the Powerballs are then tested.
They are really only tested for airtightness. The coatings don't seem to be tested for thin spots that could be easily abraded away.
This may also be suggested by the fact that a hydraulically operated knife mechanism is needed to split open the balls, as needed in the tank. If this is true, however, it means that recycling the polyethylene shell will be somewhat more of a concern. It would suggest however, that the Powerball is at least as safe in a car/truck as a tank of gasoline.
It looks from the pictures that the balls are physically cut into two halves by the hydraulic knife. The power would be needed to cut through the compressed NaH, not the polyethelene shell.

The shells are recyclable, it says. They are collected from the tank with the NaOH when you go for a refill. They are returned to the processing plant where they are recycled into more powerball coatings.

I have this vague idea, though, that there is a limit to how many times you can recycle soft plastics. Can't remember the details.

I agree that the amount of balls that you would need to carry in a car or truck are no more dangerous than a tank of gasoline. I am concerned about transport of large quantities, though. I think that would require a lot more safety precautions than they're sitting down and facing in their talk about distribution.

I also notice that they are now testing Lithium and Lithium Hydride for use in Powerballs. These promise considerably more energy content, per gallon, than Sodium Powerballs - - and more potential for problems in case of an accident. The cost will probably also be considerably higher. (Aircraft maybe?)
Yes, different applications, maybe.
 
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  • #96
THE EDISON MATERIALS TECHNOLOGY CENTER (EMTEC) Request for Proposals (RFP) DEVELOPING IMPROVED MATERIALS TO SUPPORT THE HYDROGEN ECONOMY 1.0 SUMMARY EMTEC, an Ohio membership based 501(c) 3 not-for-profit organization, is soliciting proposals to identify and fund hydrogen generation or storage projects that have near term commercialization potential. Project proposals will be accepted for hydrogen production, storage, or processing with cross-cutting materials technology aligned with the barriers and targets identified in the US Department of Energy's Hydrogen, Fuel Cells & Infrastructure Technologies Program Multi-Year Research, Development and Demonstration Plan*. It is expected that all submitted proposals will show their ability to meet the EMTEC mission which is stated as follows: “Enhance industrial competitiveness and provide economic development and wealth creation by accelerating the development, deployment, and commercialization of materials technologies through collaboration with industry, academia, and government.” *

http://www.eere.energy.gov/hydrogenandfuelcells/mypp 1

http://www.hydrogenus.com/EMTEC-EFC-RFP01A.pdf
 
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  • #97
Also, a significant link that was missed.

The International Association For Hydrogen Energy
http://www.iahe.org/
 
  • #98
Here is an example of another approach to production.
Sustained Photobiological Hydrogen Gas Production upon Reversible Inactivation of Oxygen Evolution in the Green Alga Chlamydomonas reinhardtii1
The work describes a novel approach for sustained photobiological production of H2 gas via the reversible hydrogenase pathway in the green alga Chlamydomonas reinhardtii. This single-organism, two-stage H2 production method circumvents the severe O2 sensitivity of the reversible hydrogenase by temporally separating photosynthetic O2 evolution and carbon accumulation (stage 1) from the consumption of cellular metabolites and concomitant H2 production (stage 2). A transition from stage 1 to stage 2 was effected upon S deprivation of the culture, which reversibly inactivated photosystem II (PSII) and O2 evolution. Under these conditions, oxidative respiration by the cells in the light depleted O2 and caused anaerobiosis in the culture, which was necessary and sufficient for the induction of the reversible hydrogenase. Subsequently, sustained cellular H2 gas production was observed in the light but not in the dark. The mechanism of H2 production entailed protein consumption and electron transport from endogenous substrate to the cytochrome b6-f and PSI complexes in the chloroplast thylakoids. Light absorption by PSI was required for H2 evolution, suggesting that photoreduction of ferredoxin is followed by electron donation to the reversible hydrogenase. The latter catalyzes the reduction of protons to molecular H2 in the chloroplast stroma.[continued]

The complete text or PDF is available
http://www.plantphysiol.org/cgi/content/abstract/122/1/127
 
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  • #99
water vapor is also a greenhouse gas, i wonder if that will matter.
 
  • #100
I have heard this objection made but I think when we factor in the evaporation from the worlds oceans each day, and evapotranspiration from plants on land, any contribution is insignificant.
 
  • #101
Hydrogen is not a good carrier

The hydrogen economy will not come about soon, I think. There are too many problems and costs involved. The industry is not going to pay for the entire new infrastructure and governments aren't going to either.

There are many more interesting energy carriers than hydrogen. I'm thinking of these new aluminium batteries which are being developed.

With these batteries you can ship electricity cheaply, from say Iceland to Europe. It won't be done via hydrogen, which is dangerous, cumbersome, and requires an infrastructure and plenty of energy to be produced, stored and compressed.

Aluminium batteries are so much more easy to handle, so much safer and even a tad more efficient. They're also much cheaper to manufacture, they're 50 times lighter than the batteries we know today, and they store up to 100 times more energy.

My amateur prediction of a ranking of alternative energy carriers which will dominate the near future (as far as mobile applications are concerned, cars and ships):

1. aluminium batteries
2. biofuels
3. Wind (huge strato-kites for transoceanic shipping)
4. hydrogen - fuel cells


For the grid, nuclear energy will see a renaissance over wind and solar.
 
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  • #102
Although you make some good points I do question the well-to-wheels efficiency of any battery technology. Ultimately this number reflects cost.

There are many more interesting energy carriers than hydrogen. I'm thinking of these new aluminium batteries which are being developed

The amount of energy produced by hydrogen per unit weight of fuel is about 3 times the amount of energy contained in an equal weight of gasoline, and almost 7 times that of coal. (FSEC)

http://www.hydrogenus.com/hydrogen-basics.asp

Hydrogen is an efficient carrier in liquid form. The compression and transportation is a problem though. I worked with He systems on MRI units and they constantly leaked.

Another practical problem with H2 is that it burns with an invisible flame. H2 fire detection systems are needed.
 
  • #103
I've never heard of the aluminum battery. Do you have a link to a good site about them?
 
  • #104
Ivan Seeking said:
Hydrogen is an efficient carrier in liquid form. The compression and transportation is a problem though. I worked with He systems on MRI units and they constantly leaked.

Another practical problem with H2 is that it burns with an invisible flame. H2 fire detection systems are needed.

Hey, I must admit I'm a complete amateur, but I do read up on it though. :-) I agree that hydrogen is "the best" carrier when it comes to the energy it can store, in abstracto. But it's all the little problems at the side (infrastructure, safety, production and storage, etc...) which will delay its full market introduction to a considerable extent. I think new battery systems will be explored and revolutionized first. And once we get there, you can skip the entire infrastructure problem of the hydrogen economy.


[Excuse me for my bad English, I'm not a native speaker].
 
  • #105
zoobyshoe said:
I've never heard of the aluminum battery. Do you have a link to a good site about them?


I hadn't either, and it's in its initial development stage. But it has received quite a lot of coverage so far.

When I read this, I was stunned:
"The Electric car of General Motors, EV 1, uses 736kg batteries giving a max. range of 145 km without recharge. A battery of 60 kg made with Europositron technology allows the EV 1 a max. range of 870 km without recharge."


Here's a link to the company which patented it:

http://www.europositron.com/en/index.html

If this this company is correct and succeeds in developing this battery, then it will bring about a revolution in energy storage and transportation for mobile applications.



[Excuse me for my bad English, I'm not a native speaker.]
 
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  • #106
A battery with that level of capacity would change things dramatically within far more industries than mere transportation.

For storage of H2, my vote is in a hydride. Better density than even liquid H2, slow release, and resists combustion to the point where one company claims that a lit cigarette placed into the hydride filled with H2 will extinguish on contact. Besides a requirement to be heated to release the gas, this storage method seems so much more logical than cryo or high pressure systems that could exceed the dangers of gasoline and have poor exceptance (low production/high costs) or the hassle of the pellet with its return 'product'. But I guess that's why its called engineering and not guessing. ;-)

Motor Trend has a section on the H2 economy in their August issue. Both pro/con viewpoints are presented, and the cavets of the 'promises' being touted as well. A bit negative to H2 and quite positive on the development and production of hybrid cars that can run on natural gas. Logical but shortsighted in my opinion as I don't see how natural gas production can be cleanly scaled up to fit our energy needs as well as H2. Of course, no one really has addressed the scaling issue very well though...

I can't help be amazed at what advances we're making in some regards but yet how much we have left to do in fufilling our energy needs and the brutal infancy of the 'replacement' technologies. Maybe a communist state that pooled its resources and emphasized speed over absolute quality wasn't such a bad enemy after all in terms of spurring scientific development and allowing widespread adoption across a population? 'Cause now things like an H2 economy are a line item in a campaign press release instead of a public agenda.

Maybe I just need some sleep. :-)
Cliff
 
  • #107
'Cause now things like an H2 economy are a line item in a campaign press release instead of a public agenda.

Maybe I just need some sleep. :-)

Or maybe it is just getting so close that you can taste it. This makes the obstacles even more annoying!
 
  • #108
When do we do something?

Did anyone hear the interview of T. Boone Pickens recently, in which he predicted that nationwide gasoline prices at the pump are predicted to go above $3.00 per gallon by year-end (and who can blame the producers when the world has become petroleum captives)? If not now, when do we act? Are Bush and Kerry listening, or is it just politics as usual?

KM
 
  • #109
Last night I watched a Nova [Scientific American Frontiers?] with Alan Alda. They do a nice job of highlighting a few leading H2 technologies. One funny comment made by Alda referenced the "clean laundry" smell of H2 ICE engines' exhaust.

It appears that Iceland will be a supplier of H2. Also, the solid state Hydrogen storage methods do look very encouraging! As one GM R&D, automotive engineer pointed out, if this Solid State H2 pans out this game will change very quickly. "Build them and they will come", he said.
 
  • #110
Here we go. You can watch the video online.

See the top of this page:
http://www.pbs.org/saf/1403/index.html
 
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  • #111
I almost forgot the best quote from Alda: "That will be a thing that people do; smelling each others tailpipes". :biggrin:
 
  • #112
(Following are a few comments on the forst two pages of this string. If /when I get a chance, I'll continue.)

(Quote - Janitor: If it gets to where the average citizen of India and China lives the middle-class lifestyle of a typical Westerner, I shudder to think what our air and water may become.)

I agree, but barring some kind of global catastrophe, I think it is inevitable, and they have as much right to the "good life" as we do. We nooe do exert more effort to finding our way around the problem before it becomes a disaster.

(Quote russ_watters: Yeah, but there is of course a difference - an important one. For oil/coal the sun and Earth already did 99% of the work to make it - with H2, we have to do all of the work to make it.)

Not really true! When the 'cracking' processes, etc, and other refining and environmental costs are taken into consideration, the production effort that goes into gasoline is considerable (unless you're lumping diesel fuel into that equation - - and it has its environmental problems too). The fact that we're only starting to look seriously at hydrogen derivation doesn't mean that it won't be cheaper in the near future (in fact there are some promising trends). The question here is "Who will be the 'winners' and who will be the 'losers' among the industry groups? In other words, who is going to fight this change 'to the death' to avoid losing their priviledged income sources?

(Quote Ivan Seeking: We don't do the work; nature does by solar powered chemical, biological, or even chemically powered mechanisms such as chemosynthesis. The same for fossil fuels.

Look guys, no one argues that H2 must be produced. AFAWK, we have no ready made reserves for H2 available as we do fossil fuels.)

It is true that hydrogen must be separated from its source compounds, but it is here and it is very, very plentiful (The oceans are full of it as are all of our hydrocarbon sources - there's nothing more abundant in the universe, and only a few elements here on earth). The question is that of 'extracting it' and at least, we don't have to drill down miles to get it in many cases. We also must remember that where "crude oil" comes in nature, gasoline does not; it still must be refined out, and that isn't free. The only real advantage to gasoline Today is the fact that its production infrastructure is 'in place', though not nearly to the level needed to meet Tomorrow's fuel needs, so why not make the 'new infrastructure' something else?

(Quote russ_watters: Politicians (the people driving the issue) for the most part completely ignore the issue of manufacturing the hydrogen. And that's a dealbreaker for the whole idea.)

Maybe not! There appear to be a few promising developments on the horizon - - if the vested interests don't succeed in killing them, and if the politicians are serious and not just playing politics as usual.)

(Quote Cliff_J: And I think this is the main stumbling block/selling point beyond the glassy eyed notion that H2 can work only with exclusive fuel cells produced by hand in the lab. The ICE is here to stay short-term, and the additional costs to equip/retrofit to FFVs that could handle H2 would be pretty insignificant long-term.)

I agree totally with this

(Quote Cliff_J: It'd be interesting to see which oil distribution companies make the journey or completely miss the target like the number of ice-box manufacturers and ice processing companies who embraced the refridgerator. (zero))

I think that they (almost) all will. It's of little consequence to them in the long run (for the most part) whether they make their profits from petroleum or hydrogen. The ones to watch are the drillers, the additive producers, the tanker companies and Opec. They'll fight to the death.

(Quote russ_watters: That would be a deal-breaker due to H2's efficiency as a storage medium when you recover the energy in an ICE vs fuel cells (30% vs 90%). I don't think there is any question that fuel cells can be mass produced - that they haven't is simply a matter of demand.)

I disagree. The practical efficiency of production model" fuel cells will not be nearly as high as the proponents would have us believe. Also the efficiency of the ICE need not be as low as are the present ones. The old Otto cycle is probably the lowest in efficiency of them all, but hangs on because it is so cheap to produce (mainly because of a century of experience). What we need to do is look at the 'continuous burn' engines rather than the, what I call 'pop pop' types. The continuous burn types are usually simpler, more efficient (once maturely developed), much longer lasting (a possible drawback to the producers, who want you coming back for more) and virtually always much cleaner. The most obvious of such types are the Brayton Cycle engines. A couple of intriguing developments of this type are the following:

http://www.almturbine.com/
http://www.starrotor.com/indexflash.htm

I'm also not so sure that the production fuel cell can be produced economically. Only time will answer that. I am relatively sure that in won't be soon (less than 15 years). We've been working on it for over 30 years now. We can all hope, but there are no guarantees.

(Quote Ivan Seeking: This would also mean that the transportation infrastucture for power, such as oil tankers, can eventually be [mostly] dismantled. Power can be produced semi-locally using the best options for each region.

National security benefits greatly. The political and economic value of energy autonomy is hard to even imagine.

The environmental benefits are obvious and vast.

Health benefits can be estimated but I don't have that information readily available. What is the health benefit, for example, in dollars, in eliminating fossil fuel powered vehicles?)

These alone would make hydrogen worth while.
 
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  • #113
I've often wondered why there aren't any Brayton cycle cars (except at Bonneville). Jet/gas turbine engines can be made small enough to run a normal car. I think its something that should be looked into.
 
  • #114
Russ, if you watched the videos linked above you saw the T0 electric car. This thing does 0-60 mph in 3 seconds :surprise: by using Lithium Ion [laptop] batteries. I can only guess at the cost for that stack! Still, with a three hudred mile range and < 90 minute charge time, if the cost of the batteries can be checked, this car is quite practical.

Also, I saw turbine over electric being explored by MIT some years ago. I assume that someone is still playing with this approach. The stop and go requirements for autos make turbine impractical with a direct approach, but when coupled with electric the efficiencies were quite promising. I haven't heard anything about this for quite awhile though.
 
  • #115
Brayton Cycle Approach

Actually, a Brayton Cycle engine will be considerably smaller and lighter than a comparable Diesel/Otto Cicle engine. Also, Ivan Seeking is correct, the fatal drawback of the Gas Turbine (up to now, at least) has been the engine's highly inertial characteristic (after all it's basically a big flywheel). These are used extensively nowadays in aircraft, and increasingly so in boats, but in autos that lag (both in accelerating and decelerating) has been considered unacceptable to the the average driver. Both designs referenced above claim to have solved that problem, but Ivan Seeking is also correct in asserting that this point would be totally moot in a Brayton-electric hybrid. Where the engine operates best at a sustained RPM (any engine is relatively inertial, even the Otto Cycle), the electric motor is superior at incremental< ie. accelerative operation, so if you couple them additively, like in the Prius, you have the best of both worlds.

BTW, it isn't true that a gas turbine can't accelerate a vehicle well; its very high torque tells us that. The problem is that heretofore, it wouldn't accelerate itself well. The trick in a drag is to rev the engine beforehand, with the clutch out. Then when ready to go, engage the clutch. It'll suck the doors off anything that way, but I pity the poor clutch (and transmission) with that much torque hitting it. (If you remember your history, a turbine powered car ran about thirty-five years ago in the Indy 500, and ran away from everything else, until with about two laps to go, the transmission turned to silly putty.)

Back to the point, the ideal combination, as I see it would be a small Brayton cycle engine (a big one really wouldn't be needed) and a powerful electric motor (like the one in the T-Zero, that Ivan mentioned). Here, we could get the best of all worlds (almost); low pollution, light weight, good acceleration, very good fuel economy and great durability (it's figured that the Brayton cycle has about twice the life-span of the Diesel engine). And to put the icing on the cake, they'll burn just about anything (as long as it's unleaded), so it would be ideal for a hydrogen powered car. Then the only pollutants would be Oxides of Nitrogen (which occur whenever the air is heated), and water vapor; and since there would be no hydrocarbons, there would be no need to engineer the conflicting reguirements for reducing Nitrogen Oxides against those for hydrocarbons. Nitrogen Oxides could be reduced to an absolute minimum. This would be the ideal approach during the next twenty to thirty years, while we try to bring the cost and other factors of fuel cells to a point at which they are practical for use in the everyday car (and if we can't, we won't be up the proverbial creek without a paddle).

PS: If you're wondering about costs for the Lithium Ion cells, I heard somewhere that you can purchase a T-Zero somewhere (approximately) in the hundred thousand range.
 
  • #116
It is interesting to think why a high-efficiency turbine hybrid isn't more commonly discussed. It would suffer from public opinion and comparisons to Firebird I & II with the quirky 50's means of generating public interest. But otherwise it would be very well optimized, especially for large scale applications like trucking with constant loads for extended periods of time. High-torque and highly-dependable electric engines already exist in industrial applications so little development work would be needed there either. Make the transition an economical choice and watch out... :)

The T-Zero has gotten a lot of publicity and is a really neat little car. I wouldn't call it practical though, it has the features of a touring motorcycle with two extra wheels.

Cliff
 
  • #117
Most locomotives are diesel-electric too, aren't they? That seems like another place where gas turbine-electric would be better (though the batteries would be truly massive).
 
  • #118
Russ, I believe that some modern trains already use turbine over electric.

Cliff, I meant the other practical. :biggrin: Your point is a good one. I was speaking strickly in terms of performance, range, and charge time.
 
  • #119
more - - -

As promised, I'm including comments on (some of) the statements that have been made. Here are some for pages 2 and 3.


[Quote Ivan Seeking] "Even on fission my mind is still open."

I think fission will come around again once it has matured; if it can be produced econnomically, and if nothing even more economical and renewable comes along.

[Quote zoobyshoe] "Regardless, I'm very much less concerned about meltdowns than about disposal of the waste."

Remember where most of that stuff came from. Except for Plutonium, most already existed, quite radioactive, in nature. It simply took a lot of refining (at great cost) to get large enough concentrations to be useable. If necessary, we can force the users to "unrefine" the stuff (dilute it back to its original concentrations- which would still be a lot cheaper than the original refinement) and re-disperse it into nature (like the ocean floor). Of course, the users would protest loudly. They want to make as much profit as possible - - on the cheap; but if given no other choice, what would you wager that they'd do it?

[Quote Ivan Seeking] "According to the Scientific American article, in practice, electrolytic production of H2 results in a 22% efficiency- as required to create the H2. H2 production by steam reforming techniques can be over 60% efficient. "

If a renewable usage method, such as the "pellets" (ie. NaH + H20 => NaOH + H2) becomes feasible), a relative low sustaining production of Hydrogen might suffice, once there are enough of the pellets out there.

[Quote - russ watters] "I'm not sure about methane. Its certainly preferable to other forms of hydrocarbons, but it is still a hydrocarbon. Whether you convert it to hydrogen to burn in a hydrogen fuel cell, use it as methane in a fuel cell, or burn it, the chemical reaction is about the same and as a result, the pollution is about the same."

Precisely! - - - as is Natural Gas, which some bus companies tout as the "clean fuel". Presently only electricity and, for the most part, hydrogen fit that designation.

[Quote Ivan Seeking] " To me the significance is that we have passed the break even point. I would expect that for the first time, the economy of some energy options finally can compete with fossil fuels. This strikes me as being fairly significant. Also, we get a 63% reduction in ghg emissions."

- - and with many now predicting $3.00/gallon gasoline costs, I think it's slowly beginning to sink in.

Many of you [particularly Ivan Seeking] then go into promising new methods being studied for the extraction of Hydrogen. It sssounds very encouraging.
 
  • #120
- - oops! - -

I meant pages 3 and 4.
 

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