Radioactive Decay and Linear Graphing

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SUMMARY

This discussion focuses on the analysis of radioactive decay using the isotope Iodine-131, specifically determining its half-life through linear graphing of activity data. The provided data includes time in days and corresponding activity in counts per second (cts/sec). The user successfully transformed the decay equation A = Ao * e^(-λt) into a linear form, ln(A) = -λt + ln(Ao), achieving a calculated half-life of approximately 7.7 days, which aligns closely with the accepted value of over 8 days. The conversation also clarifies the algebraic manipulation of logarithmic and exponential functions relevant to this decay model.

PREREQUISITES
  • Understanding of radioactive decay principles
  • Familiarity with logarithmic functions and their properties
  • Basic skills in graphing and interpreting linear equations
  • Knowledge of half-life calculations in nuclear chemistry
NEXT STEPS
  • Study the derivation of the exponential decay formula A = Ao * e^(-λt)
  • Learn about the application of natural logarithms in scientific calculations
  • Explore graphing techniques for exponential decay data
  • Investigate the significance of R-squared values in regression analysis
USEFUL FOR

Students in chemistry or physics, educators teaching radioactive decay concepts, and anyone interested in the mathematical modeling of decay processes.

nmacholl
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Homework Statement


This particular exercise has no "problem statement" but I'll explain it in detail using all the information provided to me.

The class was presented with a table of data containing values for time (in days) and activity (in cts/sec) for a radioactive isotope Iodine-131. We are to create a Linear graph using the data and fine Iodine-131's half life.

Here's the data, Time in days first - then the activity in cts/sec.
05 | 6523
10 | 4191
15 | 2736
20 | 1722
25 | 1114
30 | 0722
35 | 0507
40 | 0315

Homework Equations


Here are the equations given to us on the table.
A = Ao^{-\lambda t}
\lambda=(ln2)/T_{1/2}

Ao=10,000 cts/sec

The Attempt at a Solution


I've fiddled with the equation and wasn't getting anywhere near a y=mx+b solution so I decided to look up first order exponential decay on the web which landed me this equation.

ln(A) = -\lambda*t + ln(Ao)

So I made a separate table using the natural log of the Activity data and graphed it which comes out linear with an R2=1, the best fit is: f(x)=-0.09x+9.2

I used the slope to determine T1/2 or half life of the sample. I calculated a value of 7.7 days - the accepted value is barely over 8 days. I believe that the equation I found for first order exponential decay is in fact correct for this case but I have no idea how to go from A = Ao^{-\lambda t} to ln(A) = -\lambda*t + ln(Ao) algebraically.

In essence my question is: Is the ln(A) = -\lambda*t + ln(Ao) correct for this particular case of atomic decay and how do I get to this equation from the equation given.

Thanks a lot!
 
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I think the equations are equivalent.

Recall that Bx = (elnB)x = exlnB

When you take the ln of both sides of A = Ao-λt

keeping in mind that B above is your Ao

Then you get lnA = -λ*t + lnAo
 
LowlyPion said:
I think the equations are equivalent.

Recall that Bx = (elnB)x = exlnB

When you take the ln of both sides of A = Ao-λt

keeping in mind that B above is your Ao

Then you get lnA = -λ*t + lnAo

Thanks a lot but I have a little problem.
Okay so if:
A = Aox // x = -λ*t
A = ex*ln(Ao)

then

ln(A) = x*ln(Ao)
ln(A) = -λ*t*ln(Ao)

Why is my version -λ*t*ln(Ao) as opposed to the correct version -λ*t+ln(Ao)? Why is it "+ln(Ao)"
 
nmacholl said:
Thanks a lot but I have a little problem.
Okay so if:
A = Aox // x = -λ*t
A = ex*ln(Ao)

then

ln(A) = x*ln(Ao)
ln(A) = -λ*t*ln(Ao)

Why is my version -λ*t*ln(Ao) as opposed to the correct version -λ*t+ln(Ao)? Why is it "+ln(Ao)"


This step is incorrect. Exponents add, not multiply.
 
LowlyPion said:
This step is incorrect. Exponents add, not multiply.

I'm a little confused, which step is incorrect?

A power raised to a power is multiplication, which is how you get A = ex*ln(Ao) no?

Since ln() is the inverse of e it shouldn't change the exponent of e correct? ln(A) = x*ln(Ao)
 
nmacholl said:
I'm a little confused, which step is incorrect?

A power raised to a power is multiplication, which is how you get A = ex*ln(Ao) no?

Since ln() is the inverse of e it shouldn't change the exponent of e correct? ln(A) = x*ln(Ao)

I think you should familiarize yourself with ln arithmetic.

eln(x) = x

ln(ex) = x

ln(ea*b) = a + b
 
LowlyPion said:
I think you should familiarize yourself with ln arithmetic.

eln(x) = x

ln(ex) = x

ln(ea*b) = a + b

If I substitute numbers in for a and b using my calculator I don't get a true statement.
a = 2
b = 5

ln(e^(a*b)) = a + b
ln(e^(10)) = 7
10 = 7

What am I doing wrong? :(
 
nmacholl said:
If I substitute numbers in for a and b using my calculator I don't get a true statement.
a = 2
b = 5

ln(e^(a*b)) = a + b
ln(e^(10)) = 7
10 = 7

What am I doing wrong? :(

Don't despair. Maybe I'm not remembering my ln math.

Sorry if I confused you at all. I'll have to look it up.
 
OK. I don't know what I was thinking, because of course it's equal to the product.

I think however that your original equation is

A = Ao*e-λt

Taking the ln of both sides:

ln(A) =ln(Ao) -λt

That makes sense. My fault. I should have recognized it immediately.
 
  • #10
LowlyPion said:
OK. I don't know what I was thinking, because of course it's equal to the product.

I think however that your original equation is

A = Ao*e-λt

Taking the ln of both sides:

ln(A) =ln(Ao) -λt

That makes sense. My fault. I should have recognized it immediately.

That certainly makes more sense than before! The worksheet must have a typo on the equation, I double checked and the handout and the -λt is the exponent of Ao and Euler's number is nowhere to be found.

Thanks a lot.
 

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