Raman Spectra: Stokes vs Anti-Stokes - Get Answers Here!

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SUMMARY

The discussion centers on the interpretation of Raman spectra, specifically distinguishing between Stokes and Anti-Stokes lines. It is established that Stokes scattering occurs more frequently than Anti-Stokes scattering, which explains the predominance of Stokes lines in Raman spectra. The rarity of Raman processes compared to Rayleigh scattering contributes to the focus on Stokes lines in instrumentation for data collection. The provided resources offer additional insights into the intensity and characteristics of Raman scattering.

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Botttom
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Hello,

In most of the papers like

http://eprints.qut.edu.au/4763/1/4763.pdf

one sees the raman spectra of crystals or molecules and the peaks are not further described (if they are stokes or antistokes). Do all the Peaks belong to the Anti-stokes-lines? And if it is so, why don't we see any stokes-lines?

Thanks
 
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Raman processes are rather rare events (compared to the Rayleigh peak), with, in general, Stokes scattering occurring more often than Anti-Stokes events. This leads to instrumentation that uses the Stokes "regime" to collect data.

Not really a source, but nevertheless some resource: http://www.raman.de/htmlEN/basics/intensityEng.html
 
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Ok thank you
 

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