Reactivity of haloalkane to SN1 reaction

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SUMMARY

The reactivity of haloalkanes in SN1 reactions is determined by the stability of the carbocation intermediate formed during the reaction. The order of reactivity for the haloalkanes discussed is C6H5CH(CL)CH3 < C6H5(CH3)2CL < (CH3)3CCL. The stability of the carbocation increases with a decrease in the partial negative charge on the carbon atom, leading to higher reactivity in SN1 reactions.

PREREQUISITES
  • Understanding of SN1 reaction mechanisms
  • Knowledge of carbocation stability factors
  • Familiarity with haloalkane structures and nomenclature
  • Basic principles of organic chemistry
NEXT STEPS
  • Research the factors affecting carbocation stability in organic reactions
  • Learn about the differences between SN1 and SN2 reaction mechanisms
  • Explore the role of solvent polarity in SN1 reactions
  • Investigate the reactivity of different haloalkanes in various nucleophilic substitution reactions
USEFUL FOR

Chemistry students, organic chemists, and anyone studying nucleophilic substitution reactions will benefit from this discussion.

gxc9800
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Homework Statement


in my book, it states that the reactivity of haloalkane in ascending order is C6H5CH(CL)CH3 <CH3)3 CCL <C6H5(CH3)2 CL ...

this involve formation of carbocation as intermediate , so i the lesser the partial negative charge on C atom during formation of carbocation ,the more stable it is , and the more reactive towards SN1 reaction.

my ans is C6H5CH(CL)CH3 < C6H5(CH3)2 CL < CH3)3 CCL

Which is correct?

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