Relaxation and retardation time for polymeric liquids

In summary, the relaxation time for polymeric liquids is the time it takes for a polymer chain to undergo a significant change in conformation after being subjected to an external force or stress. This time is affected by factors such as molecular weight, temperature, and applied stress. It is typically measured using rheological techniques and is closely related to the viscosity of the liquid. The relaxation time also plays a crucial role in the behavior and performance of polymeric liquids in different applications, with shorter relaxation times being desirable for faster production and longer relaxation times being beneficial for sustained release or better film formation.
  • #1
hanson
319
0
Hi all, I am wondering what the typical values of relaxation and retardation time for different real materials?
I know these times depend on quite a number of things.
But I just want to have a sense of the ratio of the two time scales for different real materials like blood, cervical mucus and other materials...

Do you have some good references for these data? I am kind of confused when I search online about it.
 
Chemistry news on Phys.org
  • #2
What do you mean by relaxation time and retardation time?
 
  • #3


Relaxation and retardation time are important properties of polymeric liquids that can provide insight into their behavior and properties. These times are related to the viscoelastic nature of polymeric liquids, which is a combination of both viscous and elastic behavior.

The relaxation time is the time required for a polymeric liquid to return to its original shape after being deformed. It is related to the mobility of the polymer chains and can vary greatly depending on the type of polymer and its molecular weight. For example, high molecular weight polymers will have longer relaxation times compared to low molecular weight polymers.

On the other hand, retardation time is the time required for a polymeric liquid to reach equilibrium after being subjected to a constant external force. It is related to the resistance of the polymer chains to deformation and can also vary depending on the type of polymer and its molecular weight.

The ratio of relaxation to retardation time can vary significantly for different real materials. For example, blood is a complex mixture of proteins, cells, and other components, and therefore its relaxation and retardation times will be different compared to a simple polymer solution. Additionally, the ratio can also be affected by external factors such as temperature and pressure.

As for references, there are many research articles and textbooks that discuss relaxation and retardation times for different polymeric materials. Some good starting points could be "Viscoelastic Properties of Polymers" by John D. Ferry and "Polymer Science and Technology" by Joel R. Fried. Additionally, consulting with experts in the field or reaching out to polymer research organizations may also provide valuable information and resources.
 

1. What is the relaxation time for polymeric liquids?

The relaxation time for polymeric liquids is the time it takes for a polymer chain to undergo a significant change in conformation, such as untangling or unfolding, after being subjected to an external force or stress. This time varies depending on the type of polymer and the conditions of the experiment.

2. What factors affect the relaxation time of polymeric liquids?

The relaxation time of polymeric liquids is affected by several factors, including the molecular weight and structure of the polymer, the temperature, and the presence of additives or solvents. Additionally, the applied stress or strain rate can also impact the relaxation time.

3. How is the relaxation time measured for polymeric liquids?

The relaxation time for polymeric liquids is typically measured using rheological techniques, such as dynamic mechanical analysis or oscillatory shear rheometry. These methods involve subjecting the polymer to a controlled stress or strain and monitoring its response over time.

4. What is the relationship between relaxation time and viscosity for polymeric liquids?

The relaxation time and viscosity of polymeric liquids are closely related. Generally, polymers with longer relaxation times also have higher viscosities. This is because longer relaxation times mean that the polymer chains are less mobile, leading to a slower flow and higher resistance to deformation.

5. How does relaxation time affect the behavior of polymeric liquids in different applications?

The relaxation time of polymeric liquids plays a crucial role in their behavior and performance in various applications. For example, in polymer processing, a shorter relaxation time is desirable for faster and more efficient production. On the other hand, in applications such as drug delivery or coatings, a longer relaxation time may be beneficial for sustained release or better film formation, respectively.

Similar threads

Replies
1
Views
2K
  • Biology and Chemistry Homework Help
Replies
6
Views
542
  • Biology and Medical
Replies
1
Views
942
Replies
2
Views
2K
Replies
8
Views
843
Replies
2
Views
575
  • Classical Physics
Replies
3
Views
1K
  • Other Physics Topics
Replies
14
Views
3K
  • Introductory Physics Homework Help
Replies
5
Views
367
  • Atomic and Condensed Matter
Replies
1
Views
1K
Back
Top