Schrodinger Equation: Particle in a Box

In summary, the conversation discusses a one-dimensional infinite square well with non-degenerate energy levels. An infinite potential step is placed between the walls of the well, and it is questioned whether the particle is more likely to be in the left or right well. The conversation also explores the new energy levels and wave functions of this modified system, as well as the degeneracy of the energy levels and whether they are higher or lower than the original system without the step. The potential is described as V(x)=0 for -b≤x≤-b/2 or b/2≤x≤b and V(x)=infinity everywhere else.
  • #1
jgens
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Homework Statement



We have been examining a one-dimensional infinite square well where the infinite walls are located at -b and +b. The energy levels in this quantum system are non-degenerate, that is for each energy there is only one wave function. Let us place an infinite potential step between -b/2 and +b/2.
  • Is the particle more likely to be in the left or the right infinite square well?
  • What are the new energy levels and wave functions of this modified system?
  • Are the energy levels degenerate, and if so, what is the degeneracy?
  • Are the new energies higher or lower than the box without the infinite step?

Homework Equations



Time-independent Schrodinger Equation

The Attempt at a Solution



My main question involves how to interpret this problem. In my reading, the potential is just V(x) = 0 for -b < x < a and V(x) = +infinity for a < x < b where -b/2 < a < b/2. If my reading is correct, then wouldn't the particle only be in the left square well? (Since any particle would just be reflected from the region with infinite potential)

Thanks
 
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  • #2
I read it the same way, all the step does is to reduce the width of the well.
 
  • #3
I read it to mean that V(x)=0 for -b≤x≤-b/2 or b/2≤x≤b and V(x)=infinity everywhere else.
 

1. What is Schrodinger Equation: Particle in a Box?

The Schrodinger Equation: Particle in a Box is a mathematical equation that describes the behavior of a particle confined to a one-dimensional box. It was developed by physicist Erwin Schrodinger and is a fundamental concept in quantum mechanics.

2. How does the Schrodinger Equation: Particle in a Box work?

The Schrodinger Equation: Particle in a Box uses a wave function to describe the position and momentum of a particle in a box. The wave function is a mathematical representation of the probability of finding the particle in a particular location within the box.

3. What is the significance of the Particle in a Box model?

The Particle in a Box model is important because it allows us to understand how particles behave in confined spaces, which is crucial in understanding atomic and molecular structures. It also serves as a key concept in quantum mechanics and helps us understand the wave-particle duality of matter.

4. Can the Schrodinger Equation: Particle in a Box be applied to real-world systems?

Yes, the Schrodinger Equation: Particle in a Box can be applied to real-world systems such as atoms, molecules, and even nanoscale particles. It is a powerful tool for predicting the behavior of these systems and has been validated through experimental results.

5. What are the limitations of the Schrodinger Equation: Particle in a Box?

The Schrodinger Equation: Particle in a Box is a simplified model and does not take into account the complexities of real-world systems. It assumes that the box is perfectly rigid and has infinitely high potential walls, which may not be the case in practical applications. It also does not account for interactions between particles, making it unsuitable for describing systems with multiple particles.

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