Undergrad Solution Expansion of ##A^{\mu}## when ##L \rightarrow \infty##

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The discussion centers on the expansion of the vector potential ##A^{\mu}## in quantum field theory as the volume ##L \rightarrow \infty##. The Lagrangian density is given by ##\mathscr{L} = -\frac{1}{2} (\partial_{\mu} A_{\nu})(\partial^{\mu} A^{\nu})##, leading to the equations of motion ##\Box A^{\mu}=0##. The solutions are expressed as ##A^{\mu+}## and ##A^{\mu-}##, which generalize to integrals over momentum space when transitioning to infinite volume, resulting in equations ##(4.1)## and ##(4.2)##. The discussion also highlights the importance of polarization degrees of freedom and the implications of boundary conditions in quantum field theory.

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TL;DR
I wanted to discuss the generalization of free-Maxwell's solution. More insight is very welcomed.
Please note that

I'll write ##A^{\mu} := A^{\mu}(x)## for simplicity.

I'll work in natural units.

The Lagrangian density ##\mathscr{L} = -\frac 1 2 (\partial_{\mu} A_{\nu})(\partial^{\mu} A^{\nu})## has equations of motion

$$\Box A^{\mu}=0 \tag{1}$$

We expand ##A^{\mu}## in a complete set of solutions of the harmonic equation ##(1)##

$$A^{\mu}=A^{\mu+}+A^{\mu-} \tag{2.1}$$

Where

$$A^{\mu+}=\sum_{r=0}^3 \sum_{\vec k}\Big(\frac{1}{2V \omega_{\vec k}} \Big)^{1/2} \epsilon_r^{\mu}(\vec k) a_r(\vec k)e^{-ik \cdot x} \tag{2.2}$$

$$A^{\mu-} = \sum_{r=0}^3 \sum_{\vec k}\Big(\frac{1}{2V \omega_{\vec k}} \Big)^{1/2} \epsilon_r^{\mu}(\vec k) a_r^{\dagger}(\vec k)e^{ik \cdot x} \tag{2.3}$$

And

$$V=L^3, \ \ \ \ \omega_{\vec k}:= |\vec k|=k^0$$

Alright. I started wondering why there was a volume term involved in the solution expansion. After reading a bit I understood why. It has to do with the concept of a field (which is defined at every spacetime point and describes mechanical systems with infinite degrees of freedom) and making the problem simpler.

We are dealing with the vector potential ##A(\vec x , t)## which, at a given instant of time ##t##, must take a value at every spatial point ##\vec x##.

To simplify the problem then, the mechanical system is enclosed in a cube of volume ##V=L^3## and some periodic boundary conditions are imposed

$$x \approx x+L, \ y \approx y+L, \ z \approx z+L, \tag{3}$$

I understand that by doing that, we go from having an arbitrary 3-vector ##\vec k \in \Bbb R^3## to ##\vec k \in 2\pi/L## (where the ##2\pi## factor is chosen so that the solution-expansion term ##\exp(\mp ik \cdot x)=\exp(\mp ik^0 \cdot x^0) \exp(\pm i \vec k \cdot \vec x)## is single-valued).

Thus I understand that ##(2.2)## and ##(2.3)## are solutions of the mechanical system enclosed in a 3D lattice.

Once here: what if we wanted to generalize ##(2.2)## and ##(2.3)## for an infinitely large volume ##V_{\infty}##? Well, then we should take ##L \rightarrow \infty## in our periodic boundary conditions ##(3)##. In such conditions the summation becomes an integral; i.e. (Mandl & Shaw page 12, footnote ##9##)

$$\frac{1}{V} \sum_{\vec k} \rightarrow \frac{1}{(2 \pi)^3} \int d \vec k \tag{*}$$

So I'd say that ##(2.2)## and ##(2.3)## generalize to

$$A^{\mu+}= \frac{1}{\sqrt{16 \pi^{3}}} \sum_{r=0}^3 \int d \vec k \Big(\frac{1}{\omega_{\vec k}} \Big)^{1/2} \epsilon_r^{\mu}(\vec k) \tilde a_r(\vec k)e^{-ik \cdot x} \tag{4.1}$$

$$A^{\mu-} = \frac{1}{\sqrt{16 \pi^{3}}} \sum_{r=0}^3 \int d \vec k \Big(\frac{1}{\omega_{\vec k}} \Big)^{1/2} \epsilon_r^{\mu}(\vec k) \tilde a_r^{\dagger}(\vec k)e^{ik \cdot x} \tag{4.2}$$

Comparing to ##(2.2), (2.3)## we notice that the ladder operators get rescaled

$$a_r (\vec k) \rightarrow \tilde a_r (\vec k) = \sqrt{\frac{V}{(2\pi)^3}} a_r(\vec k) \tag{5.1}$$

And

$$\tilde a_r^{\dagger} (\vec k) =\Big( \tilde a_r(\vec k) \Big)^{\dagger} \tag{5.2}$$

Do you agree with the generalization ##(4.1), (4.2)##?

Extra insight is very welcomed!

Thanks :biggrin:
 
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I agree with your (4.1) and (4.2). In fact, that's pretty standard in QFT literature.
 
But there should be only 2 polarization degrees of freedom, at least when you use the simpler solution of the quantization problem starting from a completely fixed Coulomb gauge, i.e., ##\vec{\nabla} \cdot \vec{A}^{+}|\text{phys} \rangle=0##. In this gauge it automatically follows for the the free field that ##A^0=0## and you have only the two transverse polarization degrees of freedom. You can choose them as helicity eigenfunctions ##\pm 1## (corresponding to left- and right-circularly polarized plane waves).
 
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As the volume of your box goes infinity your ladder operators blow up. Infinity isn't a number, it's a place. You can't impose boundary conditions with a non-number. That's why people usually require the field to vanish at infinity.
 
Time reversal invariant Hamiltonians must satisfy ##[H,\Theta]=0## where ##\Theta## is time reversal operator. However, in some texts (for example see Many-body Quantum Theory in Condensed Matter Physics an introduction, HENRIK BRUUS and KARSTEN FLENSBERG, Corrected version: 14 January 2016, section 7.1.4) the time reversal invariant condition is introduced as ##H=H^*##. How these two conditions are identical?

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