Solution molarity change in electrolytic cell

In summary, the conversation discusses the concentration of copper ions in an electrolysis cell after 0.4 moles of electrons pass through the cell. The correct answer is C) 1.0 M, as there is no net change in molarity in the solution after the deposition and absorption of 0.2 moles of Cu2+.
  • #1
TT0
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Homework Statement



The diagram below shows an electrolysis cell which contains 1L of an aqueous 1M copper(II)sulfate solution.

upload_2016-6-30_15-43-12.png


If 0.4 moles of electrons pass through the cell, the concentration of copper ions after passage of the charge will be

A) 0.4 M

B) 0.8 M

C) 1.0 M

D) 1.2M.

2. Homework Equations

The Attempt at a Solution



I chose C because if 0.4 moles of electrons pass through the cell, then that means 0.2 moles of Cu2+ will be deposited into the solution from the anode and that means 0.2 moles of Cu2+ will be absorbed by the cathode. This gives no net change in molarity in the solution. Is this correct?

Cheers!
 
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  • #2
Looks OK.
 
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  • #3
Thanks!
 

1. How does the molarity of a solution change in an electrolytic cell?

The molarity of a solution in an electrolytic cell can change in two ways: through dilution or concentration. Dilution occurs when the electrolytic cell is filled with a solution of lower molarity, causing the concentration of the solution to decrease. Concentration, on the other hand, occurs when the electrolytic cell is filled with a solution of higher molarity, causing the concentration of the solution to increase.

2. What factors affect the change in molarity of a solution in an electrolytic cell?

The molarity of a solution in an electrolytic cell can be affected by the amount of current flowing through the cell, the duration of the electrolysis process, and the number of moles of ions present in the solution. Additionally, the type of ions and their charge also play a role in determining the change in molarity.

3. Can the molarity of a solution in an electrolytic cell be calculated?

Yes, the change in molarity of a solution in an electrolytic cell can be calculated using the formula M1V1 = M2V2, where M1 and V1 are the initial molarity and volume of the solution, and M2 and V2 are the final molarity and volume of the solution. This calculation assumes that the volume of the solution does not change during the electrolysis process.

4. How does the change in molarity of a solution in an electrolytic cell affect the concentration of ions?

The change in molarity of a solution in an electrolytic cell directly affects the concentration of ions present in the solution. As the molarity of the solution decreases, the concentration of ions also decreases, and vice versa. This change in concentration can have an impact on the conductivity and other properties of the solution.

5. Can the molarity of a solution in an electrolytic cell be controlled?

Yes, the molarity of a solution in an electrolytic cell can be controlled by adjusting the amount of current flowing through the cell or by changing the duration of the electrolysis process. Additionally, adding more solute to the solution can also increase the molarity. However, the degree of control may vary depending on the specific conditions and variables of the electrolytic cell.

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