The discussion revolves around the hybridization of orbitals in the formation of certain chemical compounds, specifically PCl5, SF6, and IF7. Participants explore the validity of hybridization theories, particularly the involvement of d orbitals in main group compounds.
Participants express disagreement regarding the role of d orbitals in hybridization, with some asserting that the traditional theory is incorrect while others seek further clarification on the implications of this claim.
The discussion reflects uncertainty regarding the validity of hybridization theories and the specific roles of d orbitals in bonding, with no consensus reached on the new theoretical framework.
This theory has been proven wrong? What does the new theory state? With the new theory could you please explain how SF6 and IF7 forms?DrDu said:This theory has long been proven wrong. In the formation of main group compounds, d-orbitals are energetically too high to contribute in hybridization.
In terms of valence bond theory, which you seem to be learning at the moment, you would describe bonding in terms of resonating bonds.Priyadarshini said:This theory has been proven wrong? What does the new theory state? With the new theory could you please explain how SF6 and IF7 forms?
Thanks!
Oh! Thank you!DrDu said:In terms of valence bond theory, which you seem to be learning at the moment, you would describe bonding in terms of resonating bonds.