Specific heat of a monotomic gas

Click For Summary
SUMMARY

The discussion centers on calculating the specific heat of a monoatomic gas using statistical mechanics. The partition function was defined as $$z=1+e^{-\beta E_1}$$ and the average internal energy as $$=\frac{E_1 e^{-\beta E_1}}{1+e^{-\beta E_1}}$$. The specific heat was derived by taking the partial derivative of the average internal energy with respect to temperature. Participants confirmed the calculations and emphasized the importance of considering all degrees of freedom in the energy calculations.

PREREQUISITES
  • Understanding of statistical mechanics concepts, particularly partition functions.
  • Familiarity with the average internal energy calculations in thermodynamics.
  • Knowledge of the relationship between temperature and energy in thermodynamic systems.
  • Basic understanding of monoatomic gas properties and their implications in physics.
NEXT STEPS
  • Study the derivation of the specific heat for monoatomic gases using the equipartition theorem.
  • Learn about the role of translational and rotational energy in diatomic and polyatomic gases.
  • Explore the implications of the partition function in different thermodynamic systems.
  • Investigate the effects of temperature variations on the specific heat of gases.
USEFUL FOR

This discussion is beneficial for physics students, researchers in thermodynamics, and anyone studying the properties of gases in statistical mechanics.

Apashanka
Messages
427
Reaction score
15
Homework Statement
The problem is attached below
Relevant Equations
The problem is attached below
IMG_20200304_112027.jpg

Given this problem I have calculated the partition function as $$z=1+e^{-\beta E_1}$$
And calculated the average internal energy as $$<U>=\frac{E_1 e^{-\beta E_1}}{1+e^{-\beta E_1}}$$
And thereafter taking the partial derivative of <E> with respect to temp. T the specific heat obtained is option (b)...
Am I correct??
 
Last edited by a moderator:
Physics news on Phys.org
Apashanka said:
Homework Statement:: The problem is attached below
Relevant Equations:: The problem is attached below

View attachment 258085
Given this problem I have calculated the partition function as $$z=1+e^{-\beta E_1}$$
And calculated the average internal energy as $$<U>=\frac{E_1 e^{-\beta E_1}}{1+e^{-\beta E_1}}$$
And thereafter taking the partial derivative of <E> with respect to temp. T the specific heat obtained is option (b)...
Am I correct??
It looks good.
See @mjc123's post.
 
Last edited:
That deals with the electronic energy of the atoms. What other energy do they have?
 
mjc123 said:
That deals with the electronic energy of the atoms. What other energy do they have?
Yo are right. I did not notice that it was a monoatomic gas.
 
mjc123 said:
That deals with the electronic energy of the atoms. What other energy do they have?
Then what should be the answer
 
Apashanka said:
Then what should be the answer
Working that out is your job.
 
mjc123 said:
Working that out is your job.
Actually I need some help regarding this...one part I have got but how to get the next part..,can you suggest something??
 
When you have independent degrees of freedom, the energy is a sum of terms for the different degrees of freedom. For example, you usually have for a diatomic gas molecule
$$
E_\mathrm{total} = E_\mathrm{translation} + E_\mathrm{rotation}.
$$
The separability applies also to the averages,
$$
\langle E_\mathrm{total} \rangle = \langle E_\mathrm{translation}\rangle + \langle E_\mathrm{rotation} \rangle.
$$
 

Similar threads

Replies
9
Views
2K
  • · Replies 4 ·
Replies
4
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 1 ·
Replies
1
Views
3K
Replies
2
Views
2K
  • · Replies 15 ·
Replies
15
Views
2K
  • · Replies 20 ·
Replies
20
Views
4K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 3 ·
Replies
3
Views
1K
  • · Replies 1 ·
Replies
1
Views
2K