State of matter by reversing reaction

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SUMMARY

The discussion centers on the hypothetical process of expanding methane (CH4) into gaseous carbon (C) and hydrogen (H) through the reaction CH4 (g) → C(g) + 4H(g). Participants conclude that the state of carbon atoms differs when the reaction is reversed, as carbon is solid at room temperature but is represented as a gas in this hypothetical decomposition scenario. The confusion arises from the contrasting states of carbon in different chemical contexts, emphasizing the importance of understanding molecular behavior in reactions.

PREREQUISITES
  • Chemical bonding concepts, specifically C−H bonds
  • Understanding of enthalpy and thermodynamic principles
  • Knowledge of states of matter and phase changes
  • Familiarity with chemical reaction equations
NEXT STEPS
  • Research the concept of standard enthalpy of formation in detail
  • Study the properties of carbon in different states and conditions
  • Explore the implications of bond energy in chemical reactions
  • Investigate the behavior of gases versus solids in chemical reactions
USEFUL FOR

Chemistry students, educators, and anyone interested in understanding the behavior of carbon in chemical reactions and the principles of thermodynamics.

henry3369
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Homework Statement


Imagine a hypothetical process in which the methane molecule, CH4, is "expanded," by simultaneously extending all four C−H bonds to infinity. We then have the process:
CH4 (g) → C(g) + 4H(g)

Compare the reaction for the "expansion" of methane with the reverse of the reaction that represents the standard enthalpy of formation. Is the state of the carbon atoms the same or different when reversed?

Homework Equations


None

The Attempt at a Solution


According to my assignment, the state of the carbon atoms is different when the reaction is reversed.

I don't understand why Carbon is a gas when decomposed from CH4, but a solid when combined with hydrogen to form CH4. I understand that Carbon is a solid at room temperature, but then why would the decomposition result in gaseous Carbon rather than solid Carbon?
 
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henry3369 said:

Homework Statement


Imagine a hypothetical process in which the methane molecule, CH4, is "expanded," by simultaneously extending all four C−H bonds to infinity. We then have the process:
CH4 (g) → C(g) + 4H(g)

Compare the reaction for the "expansion" of methane with the reverse of the reaction that represents the standard enthalpy of formation. Is the state of the carbon atoms the same or different when reversed?

Homework Equations


None

The Attempt at a Solution


According to my assignment, the state of the carbon atoms is different when the reaction is reversed.

I don't understand why Carbon is a gas when decomposed from CH4, but a solid when combined with hydrogen to form CH4. I understand that Carbon is a solid at room temperature, but then why would the decomposition result in gaseous Carbon rather than solid Carbon?
Nevermind, it was only gas in this hypothetical situation.
 

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