Statistical physics: Landau theory liquid crystal (2D)

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SUMMARY

The discussion focuses on constructing a Landau theory model for liquid crystals confined to two dimensions, specifically addressing the order parameter defined as s = 2(Np - 0.5Nt) / Nt. The free energy expression is given as F = a + bs + cs^2 + ds^3 + es^4, where the coefficients for odd powers of s must be zero due to symmetry. The critical temperature T_critical is identified as the point where the coefficient c changes sign, indicating a phase transition from randomly aligned to oriented states. The participants confirm the approach and share insights on solving similar problems.

PREREQUISITES
  • Understanding of Landau theory in statistical physics
  • Familiarity with order parameters in phase transitions
  • Knowledge of free energy expressions and their significance
  • Basic concepts of liquid crystal behavior in two dimensions
NEXT STEPS
  • Explore the derivation of Landau free energy expansions in more detail
  • Study the implications of symmetry in phase transitions
  • Investigate the behavior of liquid crystals under varying temperature conditions
  • Learn about the mathematical techniques for analyzing stability in phase transitions
USEFUL FOR

Students and researchers in physics, particularly those focusing on statistical mechanics, liquid crystal research, and phase transition phenomena.

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Homework Statement



A simple model for liquid crystals confined to 2 dimensions is o assume each molecule can only align in one of 2 perpendicular directions. To construct a landau model its convenient to define order parameter, s :

s = 2 ( Np - 0.5Nt ) / Nt
Np - number molecules aligned parallel to some director
Nt - Np - number of molecules aligned perpendicular to some director
Nt - total number of molecules

The free energy is F = a + bs + cs^2 + ds^3 + es^4 , determine appropriate values of expressions for a, b, c, d and e for liquid crystal confined to 2 dimensions if a transition is observed from randomly aligned to oriented at some temperature T_critical.

Homework Equations

The Attempt at a Solution



I work out the order parameter for 3 configurations : s=1 (all parallel wrt director), s= -1 (all perpendicular wrt director) and s=0 (randomly aligned)

The free energy should be the same regardless of whether they are aligned parallel or perpendicular w.r.t some arbitrary direction so there should be symmetry for s = +/- 1. This means the coefficients of odd powers of 's' are zero.
F(s) is a quartic so will have 2 stable equilibria and 1 unstable equilibrium. I differentiate and get
s = 0 or s^2 = -c/2e

From what I've seen of other similar problems I am thinking that the phase transition occurs when we go to a stable equilibrium point i.e - s^2 ---> + s^2 when 'c' changes sign. This happens at T_critical so let c(T) = c(T-Tc).
Not even sure if this is right or where I go from here[/B]
 
Reading it back now it is abit wordy isn't it.
Yes I have solved it its okay. Was half way there.
 
Hi, I'm stuck trying to solve a very similar question to this. Any chance you remember your solution?
 

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