One should reformulate the Pauli exclusion principle in terms of creation and annihilation operators. Suppose we have some quantum number n=0,1,2,... and for each state we have either zero and one fermion; two fermions are forbidden by the Pauli principle.
So one allowed state is
[tex]|0,1,1,\ldots\rangle[/tex]
where we have 0 fermions for n=0, 1 fermion for n=1 and 1 fermion for n=2.
The state is created from the vacuum state by using two creation operators, i.e.
[tex]|0,1,1,\ldots\rangle = a_1^\dagger\,a_2^\dagger|0\rangle[/tex]
The Pauli principle is guarantueed by the fact that if we act with a second creation operator for n on a state where we already have one fermion for this specific n, the state is annihilated.
[tex]a_0^\dagger |0,1,1,\ldots\rangle = |1,1,1,\ldots\rangle[/tex]
[tex]a_1^\dagger |0,1,1,\ldots\rangle = 0[/tex]
[tex]a_2^\dagger |0,1,1,\ldots\rangle = 0[/tex]
or in general for a '1' at position n
[tex]|\ldots,1,\ldots\rangle \to a_n^\dagger|\ldots,1,\ldots\rangle = 0[/tex]
Now using these states with either 0 or 1 fermions for every n we can write down arbitrary superpositions.
If now use a superposition of states and act on it with a creation operator, this operator annihilates all states states with one fermion at n, and it creates a fermion in all states with zero fermions at n, i.e.
[tex]|0,0,\ldots\rangle + |0,1,\ldots\rangle + |1,1,\ldots\rangle \to a_0^\dagger(|0,0,\ldots\rangle + |0,1,\ldots\rangle + |1,1,\ldots\rangle) = |1,0,\ldots\rangle + |1,1,\ldots\rangle + 0[/tex]
In this mathematical sense the Pauli principle applies to all states, not only to specific "one particle states" or "collspsed states".