Surface Plasmon Resonance in Gold Films: My Conundrum

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Discussion Overview

The discussion centers around understanding surface plasmon resonance (SPR) in gold films, including the refractive index of gold in optical light and the relationship between negative refractive index and SPR. Participants explore theoretical aspects and seek clarification on these concepts.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant proposes that the refractive index of gold in optical light might be around 5-10, but expresses uncertainty about this value.
  • A later post suggests that the refractive index of gold is more accurately between 1.5-3 across the visible spectrum, referencing the CRC handbook.
  • Another participant mentions that negative refractive index is related to surface plasmon resonance and describes surface plasmon polaritons (SPP) as a normal mode of a metal-dielectric interface associated with negative refractive index.
  • One participant refers to a book for a detailed explanation of surface plasmon polaritons, indicating that it provides foundational knowledge on the topic.

Areas of Agreement / Disagreement

Participants express differing views on the refractive index of gold, with no consensus reached on its value. The relationship between negative refractive index and surface plasmon resonance is also discussed, but remains somewhat unclear among participants.

Contextual Notes

There are limitations in the discussion regarding the assumptions made about the refractive index and the definitions of terms like surface plasmon resonance and surface plasmon polaritons. Some mathematical aspects are referenced but not fully explored.

philip041
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I'm trying understand surface plasmon resonance in a gold film, and have decided that gold must have a refractive index of say 5-10ish in optical light. However I'm not sure and I think I might be on the wrong track.

Also does negative refractive index have anything to do with surface plasmon resonance.

Sorry got myself in a mess.
 
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philip041 said:
I'm trying understand surface plasmon resonance in a gold film, and have decided that gold must have a refractive index of say 5-10ish in optical light. However I'm not sure and I think I might be on the wrong track.

Looking in the CRC handbook, it seems it's more like 1.5-3 across the visible spectrum.

Also does negative refractive index have anything to do with surface plasmon resonance.

I don't know enough about SPR to answer that. I always assumed it was a nonlinear-optical-effect thing?
 


I know something about ssp, and negative refractive index has all about plasmons resonance... SPP is a normal mode of a metal-dielectric interface whom is accomplished by a negative refractive index.

SPP is a solution of a MAXWELL's equation.. check boundary condition and normal modes definition (JACKSON chapter 7 and any book of mathematics)..

Good luck
 


For an excellent explanation of surface plasmon polaritons, I refer you to "Plasmonics: Fundamentals and Applications" by Stefan Maier. I found the book really helpful.

Especially Chap 1 and 2. Goes through basics and what plasmons are about.
 

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