Temperature inside a box as particles escape a small hole

In summary, the conversation discusses the effusion of a perfect gas from a container into a vacuum and the resulting change in temperature inside the container. The equations for particle flux, average kinetic energy, and escaping energy are given. The attempt at a solution involves finding an expression for the temperature inside the container, taking into account the rate of effusion and the initial temperature. The conversation also addresses the use of LaTeX syntax for equations.
  • #1
igowithit
6
1

Homework Statement


Edit: Thanks to gneill for showing me the LaTeX ropes. Equations should work now.

A perfect gas enclosed within a container escapes into vacuum through a small circular hole. The particle flux through the hole is ##\frac{nc}{4}## and the energy per particle escaping can be found to be 2kT. Assuming that the volume of the container is fixed, find an expression for the temperature inside the box starting with an initial temperature of ##T_o##.

Homework Equations


$$J_n = \frac{nc}{4}$$
$$E_{avg} = \frac{3}{2}kT$$
$$E_{esc} = 2kT$$
$$R_{eff} = \frac{PA}{\sqrt{2\pi MRT}}$$

The Attempt at a Solution


Temperature is simply an average of the kinetic energy of all the particles. So before any particles escape, the average kinetic energy in the box is

$$E_{0} = \frac{3}{2}kT_o$$

The average kinetic energy will drop by the rate of effusion times the average kinetic energy of the escaping particles, or

$$KE_{box} = \frac{3}{2}kT_o - \frac{PA}{\sqrt{2\pi MRT_o}}*2kT_o$$

I don't think this is quite right though. It needs an integration somewhere from ##T_o## to 0? Any nudges in the right direction are appreciated.
 
Last edited:
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  • #2
To have your LaTeX syntax recognized you need to surround it with tags. The tags for inline equations are double hash marks (#). If you use double dollar signs ($) instead, the equation will be placed centered on its own line and in a larger font.

Here's an example:

The following equation is inline in this line of text ##J_n = \frac{nc}{4}## as you can see. The next one will be placed on its own line $$E_{avg} = \frac{3}{2}kT$$ all by itself and with a larger font.

If you Reply to this post you'll be able to see the embedded tags in the quote.
 
  • #3
Kind of out of my line, but why would the particle energy leaving the box be greater than the particle energy inside the box?

And what happened to nc/4 and what are the symbols and units? Isn't THAT the effusion rate rather than your equation for Reff?
 
  • #4
igowithit said:
I don't think this is quite right though. It needs an integration somewhere from ToToT_o to 0? Any nudges in the right direction are appreciated.
The temperature is falling, so the rate of energy loss falls over time. Write an expression for the rate of loss of energy as a function of the temperature at some arbitrary moment.
What are n and c, or is it a single variable nc?
 

What is the relationship between temperature and particle escape in a box?

The temperature inside a box is directly related to the number of particles that escape through a small hole. As the temperature increases, the speed and kinetic energy of the particles also increase, making it more likely for them to escape through the hole.

How does the size of the hole affect the temperature inside the box?

The size of the hole has a direct impact on the temperature inside the box. A smaller hole will result in a higher temperature, as it restricts the number of particles that can escape, causing an increase in pressure and temperature inside the box.

What factors influence the rate of particle escape from a box?

The rate of particle escape from a box is influenced by several factors. These include the size of the hole, the temperature inside the box, the type of particles, and the pressure inside the box. All of these factors affect the speed and energy of the particles, which ultimately determines how many particles can escape through the hole.

How does the type of particles affect the temperature inside the box?

The type of particles in a box can have a significant impact on the temperature. Different types of particles have different masses and velocities, which can affect the rate of particle escape and, in turn, the temperature inside the box.

What happens to the temperature as particles continue to escape from the box?

The temperature inside the box will decrease as particles continue to escape through the hole. This is because the remaining particles have lower kinetic energy, resulting in a decrease in temperature. Eventually, the temperature will reach equilibrium, where the rate of particle escape is equal to the rate of particle collisions, resulting in a constant temperature.

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